Boron difluoride formazanates with thiophene and 3,4-ethylenedioxythiophene capping and their electrochemical polymerization

被引：15

作者：

Kumar, Chandan ^{[1
]}

Agrawal, Abhijeet R. ^{[1
]}

Ghosh, Nani Gopal ^{[1
]}

Karmakar, Himadri S. ^{[1
]}

Das, Sarasija ^{[1
]}

Kumar, Neha Rani ^{[1
]}

Banewar, Vishal W. ^{[2
]}

Zade, Sanjio S. ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res IISER Kolkata, Dept Chem Sci, Mohanpur 741246, India

[2] Inst Sci, Dept Chem, 15 Madam Cama Rd, Ft Mumbai 400032, Maharashtra, India

来源：

DALTON TRANSACTIONS | 2020年 / 49卷 / 38期

关键词：

BODIPY DYES; COMPLEXES; ELECTROCHEMILUMINESCENCE; REDUCTION; CHEMISTRY; LIGANDS;

D O I：

10.1039/d0dt02905j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report here the first example of BF2 formazanates with thiophene capping and their pi-conjugated polymers in the form of electroactive uniform thin films by electrochemical polymerization. These new formazanates and their polymers possess panchromatic absorption with low lying frontier molecular orbitals. With small band gaps (1.5-1.8 eV), they are good candidates for organic electronics and light-harvesting applications. A computational study on the charge transport properties of BF2 formazanates with 3,4-ethylenedioxythiophene (EDOT) indicates an ambipolar semiconductor nature.

引用

收藏

页码：13202 / 13206

页数：5

相关论文

共 31 条

[1] High Stokes Shift Anilido-Pyridine Boron Difluoride Dyes [J].

Araneda, Juan F. ;

Piers, Warren E. ;

Heyne, Belinda ;

Parvez, Masood ;

McDonald, Robert .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (51) :12214-12217

[2] Alkyl Chain Length Dependence of the Field-Effect Mobility in Novel Anthracene Derivatives [J].

Back, Jang Yeol ;

An, Tae Kyu ;

Cheon, Ye Rim ;

Cha, Hyojung ;

Jang, Jaeyoung ;

Kim, Yebyeol ;

Baek, Yonghwa ;

Chung, Dae Sung ;

Kwon, Soon-Ki ;

Park, Chan Eon ;

Kim, Yun-Hi .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (01) :351-358

[3] Structurally Diverse Boron-Nitrogen Heterocycles from an N2O23- Formazanate Ligand [J].

Barbon, Stephanie M. ;

Staroverov, Viktor N. ;

Gilroy, Joe B. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (28) :8173-8177

[4] Boron difluoride formazanate copolymers with 9,9-di-n-hexylfluorene prepared by copper-catalyzed alkyne-azide cycloaddition chemistry [J].

Barbon, Stephanie M. ;

Gilroy, Joe B. .

POLYMER CHEMISTRY, 2016, 7 (21) :3589-3598

[5] Effect of Extended π Conjugation on the Spectroscopic and Electrochemical Properties of Boron Difluoride Formazanate Complexes [J].

Barbon, Stephanie M. ;

Staroverov, Viktor N. ;

Gilroy, Joe B. .

JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (10) :5226-5235

[6] Substituent-Dependent Optical and Electrochemical Properties of Triarylformazanate Boron Difluoride Complexes [J].

Barbon, Stephanie M. ;

Price, Jacquelyn T. ;

Reinkeluers, Pauline A. ;

Gilroy, Joe B. .

INORGANIC CHEMISTRY, 2014, 53 (19) :10585-10593

[7] Structurally Tunable 3-Cyanoformazanate Boron Difluoride Dyes [J].

Barbon, Stephanie M. ;

Reinkeluers, Pauline A. ;

Price, Jacquelyn T. ;

Staroverov, Viktor N. ;

Gilroy, Joe B. .

CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (36) :11340-11344

[8] Fluorescent indicators based on BODIPY [J].

Boens, Noel ;

Leen, Volker ;

Dehaen, Wim .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (03) :1130-1172

[9] Boron difluorides with formazanate ligands: redox-switchable fluorescent dyes with large stokes shifts [J].

Chang, M. -C. ;

Chantzis, A. ;

Jacquemin, D. ;

Otten, E. .

DALTON TRANSACTIONS, 2016, 45 (23) :9477-9484

[10] Synthesis and ligand-based reduction chemistry of boron difluoride complexes with redox-active formazanate ligands [J].

Chang, M. -C. ;

Otten, E. .

CHEMICAL COMMUNICATIONS, 2014, 50 (56) :7431-7433

← 1 2 3 4 →