Palladium-catalysed borylsilylation of alkynes and borylsilylative carbocyclization of diynes and an enyne compound

被引：119

作者：

Onozawa, S ^{[1
]}

Hatanaka, Y ^{[1
]}

Tanaka, M ^{[1
]}

机构：

[1] NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 13期

关键词：

D O I：

10.1039/a702802d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition reactions or addition-carbocyclization reactions of a borylsilane with alkynes, alpha,omega-diynks or an enyne compound proceed efficiently in the presence of palladium catalysts, P(OCH2)(3)CEt being the ligand of choice.

引用

页码：1229 / 1230

页数：2

共 19 条

[1] TRANSITION-METAL-CATALYZED DIBORATION OF VINYLARENES
BAKER, RT
NGUYEN, P
MARDER, TB
WESTCOTT, SA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (12): : 1336 - 1338
[2] BATESON JH, 1994, ORGANOMETALLIC REAGE, P129
[3] SYNTHESIS AND REACTIVITY OF SILYLBORANES
BUYNAK, JD
GENG, BL
[J]. ORGANOMETALLICS, 1995, 14 (06) : 3112 - 3115
[4] Facile oxidative addition of the phosphorous-selenium bond to Pd(0) and Pt(0) complexes and development of Pd-catalyzed regio- and stereoselective selenophosphorylation of alkynes
Han, LB
Choi, N
Tanaka, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) : 7000 - 7001
[5] DOUBLE GERMYLATION OF UNSATURATED CARBON-COMPOUNDS WITH DIGERMANES IN THE PRESENCE OF PALLADIUM AND PLATINUM CATALYSTS
HAYASHI, T
YAMASHITA, H
SAKAKURA, T
UCHIMARU, Y
TANAKA, M
[J]. CHEMISTRY LETTERS, 1991, (02) : 245 - 248
[6] PLATINUM COMPLEX-CATALYZED DEHYDROGENATIVE MONOSILYLATION OF ALKENES WITH DISILANES
HAYASHI, T
KAWAMOTO, AM
KOBAYASHI, TA
TANAKA, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (07) : 563 - 564
[7] PALLADIUM(0)-CATALYZED THIOBORATION OF TERMINAL ALKYNES WITH 9-(ALKYLTHIO)-9-BORABICYCLO[3.3.1]NONANE DERIVATIVES - STEREOSELECTIVE SYNTHESIS OF VINYL SULFIDES VIA THE THIOBORATION CROSS-COUPLING SEQUENCE
ISHIYAMA, T
NISHIJIMA, K
MIYAURA, N
SUZUKI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (16) : 7219 - 7225
[8] Platinum(0)-catalyzed diboration of alkynes with tetrakis(alkoxo)diborons: An efficient and convenient approach to cis-bis(boryl) alkenes
Ishiyama, T
Matsuda, N
Murata, M
Ozawa, F
Suzuki, A
Miyaura, N
[J]. ORGANOMETALLICS, 1996, 15 (02) : 713 - 720
[9] PLATINUM(O)-CATALYZED DIBORATION OF ALKYNES
ISHIYAMA, T
MATSUDA, N
MIYAURA, N
SUZUKI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (23) : 11018 - 11019
[10] Mechanistic investigation of stoichiometric alkyne insertion into Pt-B bonds and related chemistry bearing on the catalytic diborylation of alkynes mediated by platinum(II) diboryl complexes
Iverson, CN
Smith, MR
[J]. ORGANOMETALLICS, 1996, 15 (24) : 5155 - 5165

← 1 2 →