Polymerization reactions in porous coordination polymers

被引:571
作者
Uemura, Takashi [1 ,2 ]
Yanai, Nobuhiro [1 ]
Kitagawa, Susumu [1 ,3 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3320012, Japan
[3] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan
关键词
LIVING RADICAL POLYMERIZATION; FRAMEWORK MATERIALS; MOLECULAR-WEIGHT; VINYL MONOMERS; GUEST REMOVAL; NANOPARTICLES; DESIGN; INFILTRATION; FABRICATION; PALLADIUM;
D O I
10.1039/b802583p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recent developments in polymerizations within the nanochannels of porous coordination polymers (PCPs) are covered in this tutorial review. The characteristic features of PCPs are regular structures, controllable channel sizes and shapes, a designable surface functionality, and. flexible frameworks, which can be utilized for precision polymer synthesis and specific polymer confinement. This review discusses promising approaches to multiple controls of polymer structures, analysis systems for low-dimensional polymer assemblies and the construction of PCP-polymer nanohybrids, which are strong enticements to researchers in the areas of inorganic, materials and polymer chemistry.
引用
收藏
页码:1228 / 1236
页数:9
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