Understanding and controlling the metal-directed assembly of terpyridine-functionalized coiled-coil peptides

被引:15
|
作者
Scheib, Kimberly A. [1 ]
Tavenor, Nathan A. [1 ]
Lawless, Matthew J. [1 ]
Saxena, Sunil [1 ]
Horne, W. Seth [1 ]
机构
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
基金
美国国家科学基金会;
关键词
ORGANIC FRAMEWORKS; PROTEIN DESIGN; COMPLEXES; SPECTROSCOPY; POLYMERS; SWITCH;
D O I
10.1039/c9cc03496j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-binding peptides are versatile building blocks in supramolecular chemistry. We recently reported a class of crystalline materials formed through a combination of coiled-coil peptide self-association and metal coordination. Here, we probe the serendipitously discovered metal binding motif that drives the assembly and apply these insights to exert rational control over structure and morphology in the materials.
引用
收藏
页码:7752 / 7755
页数:4
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