The "diindene" ArInInAr (Ar = C6H3-2,6-dipp2, dipp = C6H3-2,6-Pri2).: Dimeric versus monomeric in(I) aryls:: para-substituent effects in terphenyl ligands

被引:102
|
作者
Wright, RJ [1 ]
Phillips, AD [1 ]
Hardman, NJ [1 ]
Power, PP [1 ]
机构
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
关键词
D O I
10.1021/ja026285s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and structure of a "diindene" with significant metal-metal bonding are described. It has an In-In distance of 2.9786(5) Å, an In-In-C angle of 121.23(6)°, and an In-In bond order that is probably less than unity. Copyright © 2002 American Chemical Society.
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页码:8538 / 8539
页数:2
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