The "diindene" ArInInAr (Ar = C6H3-2,6-dipp2, dipp = C6H3-2,6-Pri2).: Dimeric versus monomeric in(I) aryls:: para-substituent effects in terphenyl ligands

被引：102

作者：

Wright, RJ ^{[1
]}

Phillips, AD ^{[1
]}

Hardman, NJ ^{[1
]}

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 29期

关键词：

D O I：

10.1021/ja026285s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structure of a "diindene" with significant metal-metal bonding are described. It has an In-In distance of 2.9786(5) Å, an In-In-C angle of 121.23(6)°, and an In-In bond order that is probably less than unity. Copyright © 2002 American Chemical Society.

引用

页码：8538 / 8539

页数：2

共 50 条

[1] The diindene ArInInAr (Ar = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-Pri2). Dimeric versus monomeric In(I) aryls: para-substituent effects in terphenyl ligands
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[2] Synthesis and characterization of 2,6-Dipp2-H3C6SnSnC6H3-2,6-Dipp2 (Dipp = C6H3-2,6-Pri2):: A tin analogue of an alkyne
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[3] The [2+4] Diels-Alder cycloadditon product of a probable dialuminene, Ar′AlAlAr′ (Ar′ = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2), with toluene
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[8] Synthesis and characterization of the very bulky phenols Ar*OH and Ar′OH (Ar* = C6H3-2,6-Trip2, Trip = C6H2-2,4,6-iPr3; Ar′ = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) and their lithium and sodium derivatives (LiOAr′)2 and (NaOAr*)2
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[9] The [2 + 4] Diels-Alder cycloadditon product of a probable dialuminene, Ar prime AlAlAr prime (Ar prime = C6H3- 2,6-Dipp 2; Dipp = C6H3-2,6-Pri2), with toluene
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[10] Synthesis and characterization of the monomeric sterically encumbered diaryls E{C6H3-2,6-(C6H3-2,6-Pri2)2}2 (E = Ge, Sn, or Pb)
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