Synthesis and Surface Activity Study of a Novel Branched Fluorinated Anion Surfactant with CF3CF2CF2C(CF3)2 Group

被引：19

作者：

Sha, Min ^{[1
]}

Pan, Renming ^{[1
]}

Zhan, Lewu ^{[1
]}

Xing, Ping ^{[2
]}

Jiang, Biao ^{[1
,2
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, CAS Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2014年 / 32卷 / 10期

基金：

中国国家自然科学基金;

关键词：

branched fluorinated anion surfactant; PFOA; PFOS; surface tension; BIOMEDICAL USES; AGENTS;

D O I：

10.1002/cjoc.201400377

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel branched fluorinated anion surfactant 4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis-tri-fluoromethyl-pentyl)benzene lithium phosphonate was successfully synthesized via a four-step route using perfluoro-2-methyl-2-pentene as starting material. The surface activity was investigated. The result showed that the cmc value of the surfactant in water is about 1.5x10(-2) mol/L at 298 K and the surface tension of the aqueous solution is 19.2 mN/m at the cmc.

引用

页码：995 / 998

页数：4

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