Structural features of the polymer-like phase of AC(60) fullerides

被引:8
作者
Aksenov, VL [1 ]
Shakhmatov, VS [1 ]
Osipyan, YA [1 ]
机构
[1] RUSSIAN ACAD SCI,INST SOLID STATE PHYS,CHERNOGOLOVKA 142432,RUSSIA
关键词
D O I
10.1134/1.567143
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A new approach is proposed for describing the deformation of the C-60 molecule in the polymer-like phase of the fullerides AC(60) (A=K, Rb). A discrete basis of orientational states of the molecule is introduced, and orientational ordering is described on the basis of a phenomenological theory. A symmetry analysis of the molecular vibrations in the Fm3m phase is performed. It is shown that small rotations of the C-60 can occur at a phase transition. (C) 1996 American Institute of Physics.
引用
收藏
页码:120 / 126
页数:7
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