Facile synthesis of brownmillerite-type oxides Ba2In2-xMnxO5+x through a microwave-assisted process

被引：10

作者：

Jiang, Peng ^{[1
]}

Xiao, Ting ^{[1
]}

Zhou, Yuncheng ^{[1
]}

Kuang, Jianlei ^{[1
]}

Wang, Qi ^{[1
]}

Cao, Wenbin ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China

来源：

SOLID STATE SCIENCES | 2017年 / 65卷

基金：

中国国家自然科学基金;

关键词：

Microwave synthesis; Brownmillerite-type oxides; Turquoise and green color pigments; BA2IN2O5; CONDUCTIVITY; IRRADIATION; MN5+;

D O I：

10.1016/j.solidstatesciences.2016.12.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Brownmillerite-type oxides Ba2In2-xMnxO5+x {(0 <= x <= 0.6) samples showing intense turquoise to green color were synthesized through a novel microwave assisted rapid sintering method. The properties of as synthesized samples were compared with samples prepared by previously reported solid state reaction by X-ray diffraction, scanning electronic microscopy, UV-visible absorbance spectra and X-ray photoelectron spectroscopy. The X-ray diffraction patterns showed that the structure symmetry converts from orthorhombic to cubic with the increase in Mn content. And UV-visible absorbance spectra revealed that the color is tuned from turquoise to green color by manganese doping. In the as-synthesized samples, manganese is showing Mn5+ according to the X-ray photoelectron spectroscopy results. (C) 2016 Elsevier Masson SAS. All rights reserved.

引用

页码：1 / 5

页数：5

共 19 条

[1] CHEMICAL-STRUCTURE AND OXYGEN DYNAMICS IN BA2IN2O5 [J].

ADLER, SB ;

REIMER, JA ;

BALTISBERGER, J ;

WERNER, U .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (02) :675-681

[2]

Agrawal D., 2006, Trans. Indian Cer. Soc, V65, P129, DOI [10.1080/0371750X.2006.11012292, DOI 10.1080/0371750X.2006.11012292]

[3] APPLICATION OF MICROWAVE-HEATING TECHNIQUES FOR THE SYNTHESIS OF SOLID-STATE INORGANIC-COMPOUNDS [J].

BAGHURST, DR ;

MINGOS, DMP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (12) :829-830

[4] Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni [J].

Biesinger, Mark C. ;

Payne, Brad P. ;

Grosvenor, Andrew P. ;

Lau, Leo W. M. ;

Gerson, Andrea R. ;

Smart, Roger St. C. .

APPLIED SURFACE SCIENCE, 2011, 257 (07) :2717-2730

[5] Rapid microwave synthesis of indium filled skutterudites: An energy efficient route to high performance thermoelectric materials [J].

Biswas, Krishnendu ;

Muir, Sean ;

Subramanian, M. A. .

MATERIALS RESEARCH BULLETIN, 2011, 46 (12) :2288-2290

[6]

Crist B.V., 2000, Handbook of Monochromatic XPS spectra: The Elements of Native Oxides, P548

[7] OXIDE-ION CONDUCTION IN BA2IN2O5 AND BA3IN 2CEO8, BA3IN2HFO8, OR BA3IN2ZRO8 [J].

GOODENOUGH, JB ;

RUIZDIAZ, JE ;

ZHEN, YS .

SOLID STATE IONICS, 1990, 44 (1-2) :21-31

[8] Intense Turquoise and Green Colors in Brownmillerite-Type Oxides Based on Mn5+ in Ba2In2-xMnxO5+x [J].

Jiang, Peng ;

Li, Jun ;

Ozarowski, A. ;

Sleight, Arthur W. ;

Subramanian, M. A. .

INORGANIC CHEMISTRY, 2013, 52 (03) :1349-1357

[9] Transport properties of solid oxide electrolyte ceramics: a brief review [J].

Kharton, VV ;

Marques, FMB ;

Atkinson, A .

SOLID STATE IONICS, 2004, 174 (1-4) :135-149

[10] Silicon Carbide Whiskers: Preparation and High Dielectric Permittivity [J].

Kuang, Jianlei ;

Cao, Wenbin .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (09) :2877-2880

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