CuTCPP hybridized Bi2MoO6 composite with enhanced photocatalytic activity

被引:4
作者
Zhang, Zhijie [1 ]
Huang, Hairui [1 ]
Sun, Shu [1 ]
Xu, Jiayue [1 ]
Zhang, Na [1 ]
机构
[1] Shanghai Inst Technol, Sch Mat Sci & Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China
基金
中国国家自然科学基金;
关键词
CuTCPP; Bi2MoO6; photocatalysis; composite materials; semiconductors; DYE-SENSITIZED TIO2; LIGHT; NANOPARTICLES; HETEROJUNCTION; NANOCOMPOSITE; PORPHYRINS; HYDROGEN;
D O I
10.1142/S108842461850044X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In order to increase the availability of the solar light, a Cu(II) meso- tetra(4-carboxyphenyl) porphyrin (CuTCPP) sensitizer was introduced into Bi2MoO6 photocatalyst. The obtained CuTCPP/ Bi2MoO6 composite exhibited much enhanced photocatalytic activity in the degradation of rhodamine B (RhB) under both simulated solar light and visible light beyond the absorption edge of Bi2MoO6 (lambda > 500 nm), which can be attributed to the broadened photo-response range, as well as the increased charge separation rate of the CuTCPP/Bi2MoO6 composite. Our study demonstrates that hybridizing with porphyrin derivatives can be an effective strategy to increase the utilization rate of the solar light efficiently in a photocatalytic system.
引用
收藏
页码:469 / 474
页数:6
相关论文
共 22 条
[11]   Synthesis, characterization and enhanced visible light photocatalytic activity of Bi2MoO6/Zn-Al layered double hydroxide hierarchical heterostructures [J].
Li, Haiping ;
Deng, Quanhua ;
Liu, Jingyi ;
Hou, Wanguo ;
Du, Na ;
Zhang, Renjie ;
Tao, Xutang .
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (04) :1028-1037
[12]   Role of Interparticle Charge Transfers in Agglomerated Photocatalyst Nanoparticles: Demonstration in Aqueous Suspension of Dye-Sensitized TiO2 [J].
Park, Yiseul ;
Kim, Wooyul ;
Monllor-Satoca, Damian ;
Tachikawa, Takashi ;
Majima, Tetsuro ;
Choi, Wonyong .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (01) :189-194
[13]  
Shem A. B., 2004, PHOTOSYNTH RES, V81, P239
[14]   Efficient photo-degradation of 4-nitrophenol by using new CuPp-TiO2 photocatalyst under visible light irradiation [J].
Sun, Wan-jun ;
Li, Jun ;
Yao, Gui-ping ;
Jiang, Min ;
Zhang, Feng-xing .
CATALYSIS COMMUNICATIONS, 2011, 16 (01) :90-93
[15]   Facile solvothermal synthesis of hierarchical flower-like Bi2MoO6 hollow spheres as high performance visible-light driven photocatalysts [J].
Tian, Guohui ;
Chen, Yajie ;
Zhou, Wei ;
Pan, Kai ;
Dong, Youzhen ;
Tian, Chungui ;
Fu, Honggang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (03) :887-892
[16]  
Wang C., 2009, APPL CATAL B-ENVIRON, V89, P448
[17]   Enhancement of visible photocatalytic performances of a Bi2MoO6-BiOCl nanocomposite with plate-on-plate heterojunction structure [J].
Yue, Du ;
Chen, Daimei ;
Wang, Zhihong ;
Ding, Hao ;
Zong, Ruilong ;
Zhu, Yongfa .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (47) :26314-26321
[18]   Polythiophene/Bi2MoO6: A novel conjugated polymer/nanocrystal hybrid composite for photocatalysis [J].
Zhang, Zhijie ;
Zheng, Tingting ;
Xu, Jiayue ;
Zeng, Haibo .
JOURNAL OF MATERIALS SCIENCE, 2016, 51 (08) :3846-3853
[19]   Highly efficient photocatalyst Bi2MoO6 induced by blue light-emitting diode [J].
Zhang, Zhijie ;
Wang, Wenzhong ;
Ren, Jia ;
Xu, Jiehui .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 123 :89-93
[20]   P3HT/Bi2MoO6 heterojunction with enhanced photocatalytic activity [J].
Zheng, Tingting ;
Xu, Jiayue ;
Zhang, Zhijie ;
Zeng, Haibo .
MATERIALS LETTERS, 2016, 164 :640-643