Bis[1,3-bis(2-methyltetrazol-5-yl-κN4) triazenido-κN2]nickel(II)

被引：7

作者：

Lyakhov, AS ^{[1
]}

Gaponik, PN ^{[1
]}

Pytleva, DS ^{[1
]}

Voitekhovich, SV ^{[1
]}

Ivashkevich, LS ^{[1
]}

机构：

[1] Belarusian State Univ, Physicochem Res Inst, Minsk 220050, BELARUS

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104016087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Ni(BMTT)(2)], where BMTT is 1,3-bis(2-methyltetrazol-5-yl)triazenide (C4H6N11), presents a molecular complex with tridentate ligands. The tridentate mode of the ligand is realised through the central N atom of the triazene group and two N atoms of the two tetrazole rings. The [Ni(BMTT)(2)] molecule is the meridional isomer, with crystallographic (4) over bar symmetry in space group P4(2)/n. The nickel centre has a distorted octahedral environment, with two axial Ni-N bonds of 2.041 (2) Angstrom and four equatorial Ni-N bonds of 2.0739 (14) Angstrom. The molecules are linked together by van der Waals interactions only.

引用

页码：M421 / M422

页数：2

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