Adsorptive removal of phosphates from aqueous solutions

被引:112
作者
Peleka, E. N. [1 ]
Deliyanni, E. A. [1 ]
机构
[1] Aristotle Univ Thessaloniki, Dept Chem, Sect Chem Technol & Ind Chem, GR-54124 Thessaloniki, Greece
关键词
Adsorption; Inorganic materials; Isotherms; Kinetic study; Phosphates; KINETICS; GOETHITE; HYDROTALCITE; AKAGANEITE; SORPTION; WATER;
D O I
10.1016/j.desal.2008.04.050
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Phosphates removal from aqueous solutions was investigated using three different inorganic materials: laboratory synthesized goethitc, commercial alumina and commercial hydrotalcite. Equilibrium and kinetic studies were carried out to determine their sorption capacity and the rate of phosphate ions uptake. Equilibrium data were analyzed by Langmuir and Freundlich isotherms. The maximum sorption capacity at 25 degrees C was found to be 244.58 mg g (1) for calcined hydrotalcite at 500 degrees C, 192.9 for calcined hydrotalcite at 400 degrees C, 144 mg g (1) for goethite, 60 mg g (1) for hydrotalcite and 34.57 mg g(-1) for aluminumoxid S. Kinetic data followed a pseudo-second-order kinetic model.
引用
收藏
页码:357 / 371
页数:15
相关论文
共 24 条
[1]   Phosphate removal from water by red mud using crossflow microfiltration [J].
Akay, G ;
Keskinler, B ;
Çakici, A ;
Danis, U .
WATER RESEARCH, 1998, 32 (03) :717-726
[2]  
[Anonymous], 1995, STANDARD METHODS EXA
[3]   Akaganeite and goethite-type nanocrystals: synthesis and characterization [J].
Bakoyannakis, DN ;
Deliyanni, EA ;
Zouboulis, AI ;
Matis, KA ;
Nalbandian, L ;
Kehagias, T .
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 59 (01) :35-42
[4]   Removal of phosphate from aqueous solutions by electro-coagulation [J].
Bektas, N ;
Akbulut, H ;
Inan, H ;
Dimoglo, A .
JOURNAL OF HAZARDOUS MATERIALS, 2004, 106 (2-3) :101-105
[5]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[6]   Removal of ammonium and phosphates from wastewater resulting from the process of cochineal extraction using MgO-containing by-product [J].
Chimenos, JM ;
Fernández, AI ;
Villalba, G ;
Segarra, M ;
Urruticoechea, A ;
Artaza, B ;
Espiell, F .
WATER RESEARCH, 2003, 37 (07) :1601-1607
[7]   Phosphate adsorption on synthetic goethite and akaganeite [J].
Chitrakar, Ramesh ;
Tezuka, Satoko ;
Sonoda, Akinari ;
Sakane, Kohji ;
Ooi, Kenta ;
Hirotsu, Takahiro .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 298 (02) :602-608
[8]  
COONEY E, 1992, WATER QUALITY MANAGE, V3, P109
[9]   Comparative study of phosphates removal from aqueous solutions by nanocrystalline akaganeite and hybrid surfactant-akaganeite [J].
Deliyanni, E. A. ;
Peleka, E. N. ;
Lazaridis, N. K. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2007, 52 (03) :478-486
[10]   Akaganeite-type β-FeO(OH) nanocrystals:: preparation and characterization [J].
Deliyanni, EA ;
Bakoyannakis, DN ;
Zouboulis, AI ;
Matis, KA ;
Nalbandian, L .
MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 42 (01) :49-57