X-ray study of molecular association in alcohols having bulky substituents

被引：1
|
作者：
Saito, Kazuya [1 ]
Hishida, Mafumi [1 ]
Koike, Kent [1 ]
Nagatomo, Shigenori [1 ]
Yamamura, Yasuhisa [1 ]
机构：
[1] Univ Tsukuba, Fac Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
来源：
CHEMICAL PHYSICS LETTERS | 2017年 / 673卷
关键词：
Liquid structure; X-ray scattering; Hydrogen bond; Coarse-graining;
D O I：
10.1016/j.cplett.2017.02.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The formation of globular associate on cooling, which was previously claimed on the basis of small dielectric constant, is supported through measuring X-ray scattering from dicyclohexylmethanol (DCHM). Radial distribution function of the DCHM molecules exhibits strong temperature dependence between 65 degrees C and 130 degrees C in contrast to a little change in that of tricyclohexylmethanol (TCHM), which is similar to DCHM but essentially non-associating in experimental conditions (95-160 degrees C). (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：74 / 77
页数：4
相关论文
共 50 条
  • [1] An energy dispersive x-ray scattering and molecular dynamics study of liquid dimethyl carbonate
    Gontrani, Lorenzo
    Russina, Olga
    Marincola, Flaminia Cesare
    Caminiti, Ruggero
    JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (24)
  • [2] X-ray study of the structure of liquid water
    Fu, Ling
    Bienenstock, Arthur
    Brennan, Sean
    JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (23)
  • [3] A study of cyclohexane, piperidine and morpholine with X-ray diffraction and molecular simulations
    Gontrani, Lorenzo
    Ramondo, Fabio
    Caracciolo, Giulio
    Caminiti, Ruggero
    JOURNAL OF MOLECULAR LIQUIDS, 2008, 139 (1-3) : 23 - 28
  • [4] The structure of liquid N-methyl pyrrolidone probed by x-ray scattering and molecular simulations
    Gontrani, Lorenzo
    Caminiti, Ruggero
    JOURNAL OF CHEMICAL PHYSICS, 2012, 136 (07)
  • [5] X-ray study of surfaces and interfaces
    Asadchikov, VE
    Bukreeva, IN
    Duparré, A
    Kozhevnikov, IV
    Krivonosov, YS
    Morawe, C
    Pyatakhin, MV
    Steinert, J
    Vinogradov, AV
    Ziegler, E
    OPTICAL METROLOGY ROADMAP FOR THE SEMICONDUCTOR, OPTICAL, AND DATA STORAGE INDUSTRIES II, 2001, 4449 : 253 - 264
  • [6] Structural X-ray study of dichloroalkanes
    Drozdowski, H
    JOURNAL OF MOLECULAR LIQUIDS, 2005, 122 (1-3) : 32 - 37
  • [7] Liquid structure of 1-propanol by molecular dynamics simulations and X-ray scattering
    Akiyama, I
    Ogawa, M
    Takase, K
    Takamuku, T
    Yamaguchi, T
    Ohtori, N
    JOURNAL OF SOLUTION CHEMISTRY, 2004, 33 (6-7) : 797 - 809
  • [8] X-ray study of the roughness of surfaces and interfaces
    Kozhevnikov, IV
    Asadchikov, VE
    Bukreeva, IN
    Duparré, A
    Krivonosov, YS
    Morawe, C
    Ostashev, VI
    Pyatakhin, MV
    Ziegler, E
    OPTICAL METROLOGY ROADMAP FOR THE SEMICONDUCTOR, OPTICAL, AND DATA STORAGE INDUSTRIES, 2000, 4099 : 267 - 278
  • [9] X-ray study of concave surface roughness
    Bukreevaa, IN
    Asadchikov, VE
    Gilev, ON
    Havronin, NA
    Kozhevnikov, IV
    Krivonosov, YS
    Ostashev, VI
    Sagitov, SI
    OPTICAL FABRICATION AND TESTING, 1999, 3739 : 395 - 403
  • [10] Liquid Structure of 1-Propanol by Molecular Dynamics Simulations and X-Ray Scattering
    Isao Akiyama
    Masaya Ogawa
    Keiichi Takase
    Toshiyuki Takamuku
    Toshio Yamaguchi
    Norikazu Ohtori
    Journal of Solution Chemistry, 2004, 33 : 797 - 809
12345