Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

被引：24
|
作者：
Angersbach-Bludau, Friedrich [1 ]
Schulz, Christopher [1 ]
Schoeffel, Julia [1 ]
Burger, Peter [1 ]
机构：
[1] Univ Hamburg, Inst Anorgan & Angew Chem, FB Chem, D-20146 Hamburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 63期
关键词：
IRON;
D O I：
10.1039/c4cc03624g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The syntheses and X-ray crystal structures of dinuclear mu-azido and mu-nitrido bridged iridium complexes bearing the pyridine, diimine ligand (PDI) are reported. Their electronic structures and formal oxidation states of the metal centers are analyzed by theoretical and experimental methods, revealing the non-innocence of the PDI and nitrido ligands.
引用
收藏
页码：8735 / 8738
页数：4
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