Reduction of azides to amines with SmI2 or Cp(2)TiCl(2)-Sm system

被引：20
作者：
Huang, Y
Zhang, YM
Wang, YL
机构：
[1] HANGZHOU UNIV,DEPT CHEM,HANGZHOU 310028,PEOPLES R CHINA
[2] HENAN NORMAL UNIV,DEPT CHEM,XINXIANG 453002,PEOPLES R CHINA
来源：
SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 15期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1080/00397919608005227
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Azides can be rapidly reduced to corresponding amines with SmI2 (Method A) or Cp(2)TiCl(2)-Sm system (Method B) in good yields under mild conditions.
引用
收藏
页码：2911 / 2915
页数：5
相关论文
共 11 条
[1]   HEXAMETHYLDISILATHIANE - ITS USE IN THE CONVERSION OF AROMATIC AND HETEROAROMATIC AZIDES TO AMINES [J].
CAPPERUCCI, A ;
DEGL'INNOCENTI, A ;
FUNICELLO, M ;
MAURIELLO, G ;
SCAFATO, P ;
SPAGNOLO, P .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (07) :2254-2256
[2]   REDUCTIVE CLEAVAGE OF C-S BOND BY SAMARIUM DIIODIDE - A NOVEL METHOD FOR THE SYNTHESIS OF DISULFIDES AND THIOLESTERS [J].
JIA, XS ;
ZHANG, YM ;
ZHOU, XJ .
TETRAHEDRON LETTERS, 1994, 35 (47) :8833-8834
[3]   REDUCTIVE CLEAVAGE OF S-S BOND IN DIPHENYL DISULFIDE BY SAMARIUM DIIODIDE - A NOVEL METHOD FOR THE SYNTHESIS OF THIOLESTERS [J].
JIA, XS ;
ZHANG, YM ;
ZHOU, XJ .
SYNTHETIC COMMUNICATIONS, 1994, 24 (03) :387-392
[4]   APPLICATION OF LANTHANIDE REAGENTS IN ORGANIC-SYNTHESIS [J].
MOLANDER, GA .
CHEMICAL REVIEWS, 1992, 92 (01) :29-68
[5]   FACILE REDUCTION OF AZIDES WITH SODIUM-BOROHYDRIDE COPPER (II) SULFATE SYSTEM [J].
RAO, HSP ;
SIVA, P .
SYNTHETIC COMMUNICATIONS, 1994, 24 (04) :549-555
[6]  
SANDLER SR, 1971, ORGANIC FUNCTIONAL G, V2, P268
[7]  
SARKAR RA, 1994, J ORG CHEM, V59, P4114
[8]   REDUCTION OF AZIDES TO AMINES WITH BOROHYDRIDE EXCHANGE RESIN - NICKEL ACETATE [J].
YOON, NM ;
CHOI, JS ;
SHON, YS .
SYNTHETIC COMMUNICATIONS, 1993, 23 (21) :3047-3053
[9]   SOME DEOXYGENATION AND REDUCTION REACTIONS WITH SAMARIUM DIIODIDE [J].
ZHANG, YM ;
LIN, RH .
SYNTHETIC COMMUNICATIONS, 1987, 17 (03) :329-332
[10]   REDUCTIVE CLEAVAGE OF SE-SE AND TE-TE BOND BY SAMARIUM DIIODIDE - SYNTHESIS OF SELENOESTERS, TELLUROESTERS, UNSYMMETRICAL ALKYLPHENYL SELENIDES AND TELLURIDES [J].
ZHANG, YM ;
YU, YP ;
LIN, RH .
SYNTHETIC COMMUNICATIONS, 1993, 23 (02) :189-193
12