Two novel three-dimensional Nd-adipates: influence of hydrothermal reaction temperature on framework topology

被引：30
作者：
Borkowski, LA
Cahill, CL
机构：
[1] George Washington Univ, Dept Chem, Washington, DC 20052 USA
[2] Carnegie Inst Washington, Geophys Lab, Washington, DC 20015 USA
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 06期
关键词：
metal-organic framework; hydrothermal; crystal structure;
D O I：
10.1016/j.inoche.2004.04.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel three dimensional neodymium adipates have been synthesized through hydrothermal techniques. Both GWMOF-1 (C6H8O4)(3)Nd-2(H2O2) and GWMOF-2 ((C6H8O4)(3)Nd-2(H2O) . H2O) are constructed of chains of edge-shared NdO8(H2O) polyhedra that are cross-linked by adipic acid molecules to form framework structures. The structures differ in the conformations of the acid chains and the resulting framework topologies. Both materials are thermally stable to approximately 370 degreesC. (C) 2004 Elsevier B.V. All rights reserved.
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页码：725 / 728
页数：4
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