Expired Drug (pantoprazole sodium) as a Corrosion Inhibitor for High Carbon Steel in Hydrochloric Acid Solution

被引:67
作者
Fouda, A. S. [1 ]
Ibrahim, H. [2 ]
Rashwaan, S. [2 ]
El-Hossiany, A. [3 ]
Ahmed, R. M. [1 ]
机构
[1] El Mansoura Univ, Fac Sci, Dept Chem, Mansoura 35516, Egypt
[2] Suez Canal Univ, Dept Chem, Fac Sci, Ismailia, Egypt
[3] Delta Fertilizers Co Talkha, Talkha, Dakahlia Govern, Egypt
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2018年 / 13卷 / 07期
关键词
Corrosion inhibition; HCl; HCS; EPS drug; AFM; FT-IR; SEM; MILD-STEEL; ADSORPTION; COPPER; DERIVATIVES; ALUMINUM; BEHAVIOR; HCL;
D O I
10.20964/2018.07.33
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The expired pantoprazole sodium EPS drug was studied as a corrosion inhibitor for high carbon steel (HCS) in 1 M HCl solution using mass loss (ML), potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) tests. Fourier transform infrared spectroscopy (FT-IR) was utilized to identify bands of PS drug on HCS surface. Surface morphology was tested by scanning electron microscope (SEM), Atomic Force Microscopy (AFM) and Energy Dispersion Spectroscopy X-ray spectra (EDX). The effect of temperature on the corrosion process has been studied in addition of different concentrations of EPS drug. PP curves showed that the study drug is a mixed kind inhibitor. The inhibition efficiency (IP %) was improved with improving the concentration of PS and was reduced by improving the temperature of the medium. The PS adsorbed on HCS surface was noticed to follow the Langmuir's adsorption isotherm. The outcome data gotten from electrochemical and chemical tests are in excellent agreement.
引用
收藏
页码:6327 / 6346
页数:20
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