Family of paramagnetic centers of Ce3+ ions in yttrium aluminum garnet

被引:20
作者
Asatryan, G. R. [1 ]
Kramushchenko, D. D. [1 ]
Uspenskaya, Yu. A. [1 ]
Baranov, P. G. [1 ]
Petrosyan, A. G. [2 ]
机构
[1] Russian Acad Sci, AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia
[2] Natl Acad Sci Armenia, Inst Phys Res, Yerevan 0203, Armenia
关键词
DEFECTS; CRYSTAL; YAG; SCINTILLATORS;
D O I
10.1134/S1063783414060031
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The electron paramagnetic resonance (EPR) spectra of Ce3+ ions in single crystals of yttrium aluminum garnet have been investigated. It has been found that, in addition to the usually observed EPR signals of Ce3+ ions located in the regular environment at dodecahedral sites of the crystal lattice, the spectra contain a group of less intense anisotropic lines with g-factors close to the corresponding parameters of Ce3+ ions in the regular environment. It has been concluded that the observed satellite lines belong to the family of Ce3+ ions in the immediate vicinity of which there are permutation defects that lead to a change in the strength and symmetry of the crystal field in the vicinity of the paramagnetic center.
引用
收藏
页码:1150 / 1156
页数:7
相关论文
共 17 条
[1]  
Abragam A., 1970, ELECT PARAMAGNETIC R
[2]  
Altshuler S. A., 1972, Electron Paramagnetic Resonance in Compounds of Transition Elements
[3]   SINGLE-CRYSTAL OF YAG - NEW FAST SCINTILLATOR IN SEM [J].
AUTRATA, R ;
SCHAUER, P ;
KVAPIL, J ;
KVAPIL, J .
JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1978, 11 (07) :707-708
[4]   Atomistic and electronic structure of antisite defects in yttrium aluminum garnet: Density-functional study [J].
Belen Munoz-Garcia, Ana ;
Artacho, Emilio ;
Seijo, Luis .
PHYSICAL REVIEW B, 2009, 80 (01)
[5]  
Chernov A. A., 1980, Modern Crystallography
[6]   LuAG:Ce fibers for high energy calorimetry [J].
Dujardin, C. ;
Mancini, C. ;
Amans, D. ;
Ledoux, G. ;
Abler, D. ;
Auffray, E. ;
Lecoq, P. ;
Perrodin, D. ;
Petrosyan, A. ;
Ovanesyan, K. L. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (01)
[7]   OXYGEN COORDINATES OF COMPOUNDS WITH GARNET STRUCTURE [J].
EULER, F ;
BRUCE, JA .
ACTA CRYSTALLOGRAPHICA, 1965, 19 :971-&
[8]   Paramagnetic impurity defects in LuAG:Ce thick film scintillators [J].
Laguta, Valentin V. ;
Slipenyuk, Alla M. ;
Glinchuk, Maya D. ;
Bykov, Igor P. ;
Zorenko, Yurij ;
Nikl, Martin ;
Rosa, Jan ;
Nejezchleb, K. .
RADIATION MEASUREMENTS, 2007, 42 (4-5) :835-838
[9]   PARAMAGNETIC RESONANCE OF CE3+ IN YTTRIUM ALUMINUM GARNET [J].
LEWIS, HR .
JOURNAL OF APPLIED PHYSICS, 1966, 37 (02) :739-&
[10]   PROPERTIES OF THE YAG-CE SCINTILLATOR [J].
MOSZYNSKI, M ;
LUDZIEJEWSKI, T ;
WOLSKI, D ;
KLAMRA, W ;
NORLIN, LO .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1994, 345 (03) :461-467