Synthesis, structure and characterisation of a Mn(IV) complex with a potentially tridentate phosphinothiol ligand

被引：7

作者：

Pérez-Lourido, P

Romero, J

Rodríguez, L

García-Vázquez, JA

Castro, J

Sousa, A ^{[1
]}

Dilworth, JR

Nascimento, OR

机构：

[1] Univ Santiago de Compostela, Fac Quim, Dept Quim Inorgan, Santiago De Compostela 15706, Spain

[2] Univ Vigo, Dept Quim Inorgan, Pontevedra 36200, Spain

[3] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[4] Univ Sao Paulo, Intituto Fis Sao Carlos, Sao Paulo, Brazil

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 05期

关键词：

crystal structure; Mn(IV) complexes; phosphinothiolate complexes; cyclic voltammetry;

D O I：

10.1016/S1387-7003(02)00392-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The manganese(IV) complex, [Mn{PhP(C6H4S-2)(2)}(2)], was synthesised by direct reaction between manganese(II) acetate and the proligand bis(2-mercaptophenyl)phenylphosphine in methanol and characterised by elemental analysis, mass spectrometry, cyclic voltammetry and X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：337 / 339

页数：3

共 6 条

[1] COORDINATION CHEMISTRY AND CATALYSIS WITH HEMILABILE OXYGEN PHOSPHORUS LIGANDS [J].