AgPd nanoparticles supported on MIL-101 as high performance catalysts for catalytic dehydrogenation of formic acid

被引：108
作者：
Dai, Hongmei [1 ]
Cao, Nan [1 ]
Yang, Lan [1 ]
Su, Jun [3 ]
Luo, Wei [1 ,2 ]
Cheng, Gongzhen [1 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
[2] Wuhan Univ, Suzhou Inst, Suzhou 215123, Jiangsu, Peoples R China
[3] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430072, Hubei, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 29期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS; HYDROGEN-STORAGE MATERIALS; EFFICIENT CATALYST; PD NANOPARTICLES; AMMONIA-BORANE; SELECTIVE DECOMPOSITION; SYNERGISTIC CATALYSIS; ALLOY NANOPARTICLES; RUTHENIUM COMPLEX; ROOM-TEMPERATURE;
D O I：
10.1039/c4ta02066a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Bimetallic AgPd nanoparticles were successfully immobilized into the metal-organic frameworks (MIL-101), and tested for their catalytic dehydrogenation of formic acid. These catalysts were composition dependent for the catalytic activity. Among all the AgPd@MIL-101 catalysts tested, the Ag20Pd80@MIL-101 catalyst exhibits the highest catalytic activity for the conversion of formic acid to high-quality hydrogen at 80 degrees C with a TOF value of 848 h(-1), which is among the highest values reported at 80 degrees C.
引用
收藏
页码：11060 / 11064
页数：5
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