AgPd nanoparticles supported on MIL-101 as high performance catalysts for catalytic dehydrogenation of formic acid

被引：110

作者：

Dai, Hongmei ^{[1
]}

Cao, Nan ^{[1
]}

Yang, Lan ^{[1
]}

Su, Jun ^{[3
]}

Luo, Wei ^{[1
,2
]}

Cheng, Gongzhen ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China

[2] Wuhan Univ, Suzhou Inst, Suzhou 215123, Jiangsu, Peoples R China

[3] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430072, Hubei, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 29期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; HYDROGEN-STORAGE MATERIALS; EFFICIENT CATALYST; PD NANOPARTICLES; AMMONIA-BORANE; SELECTIVE DECOMPOSITION; SYNERGISTIC CATALYSIS; ALLOY NANOPARTICLES; RUTHENIUM COMPLEX; ROOM-TEMPERATURE;

D O I：

10.1039/c4ta02066a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bimetallic AgPd nanoparticles were successfully immobilized into the metal-organic frameworks (MIL-101), and tested for their catalytic dehydrogenation of formic acid. These catalysts were composition dependent for the catalytic activity. Among all the AgPd@MIL-101 catalysts tested, the Ag20Pd80@MIL-101 catalyst exhibits the highest catalytic activity for the conversion of formic acid to high-quality hydrogen at 80 degrees C with a TOF value of 848 h(-1), which is among the highest values reported at 80 degrees C.

引用

页码：11060 / 11064

页数：5

共 63 条

[1] Ligand design for functional metal-organic frameworks [J].

Almeida Paz, Filipe A. ;

Klinowski, Jacek ;

Vilela, Sergio M. F. ;

Tome, Joao P. C. ;

Cavaleiro, Jose A. S. ;

Rocha, Joao .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (03) :1088-1110

[2] Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions [J].

Bi, Qng-Yuan ;

Du, Xian-Long ;

Liu, Yong-Mei ;

Cao, Yong ;

He, He-Yong ;

Fan, Kang-Nian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (21) :8926-8933

[3] Iron-Catalyzed Hydrogen Production from Formic Acid [J].

Boddien, Albert ;

Loges, Bjorn ;

Gaertner, Felix ;

Torborg, Christian ;

Fumino, Koichi ;

Junge, Henrik ;

Ludwig, Ralf ;

Beller, Matthias .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8924-8934

[4] Metal-organic framework growth at functional interfaces: thin films and composites for diverse applications [J].

Bradshaw, Darren ;

Garai, Ashesh ;

Huo, Jia .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (06) :2344-2381

[5] Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium [J].

Bulushev, Dmitri A. ;

Jia, Lijun ;

Beloshapkin, Sergey ;

Ross, Julian R. H. .

CHEMICAL COMMUNICATIONS, 2012, 48 (35) :4184-4186

[6] Palladium supported on an acidic metal-organic framework as an efficient catalyst in selective aerobic oxidation of alcohols [J].

Chen, Gongzhou ;

Wu, Shijian ;

Liu, Hongli ;

Jiang, Huanfeng ;

Li, Yingwei .

GREEN CHEMISTRY, 2013, 15 (01) :230-235

[7] Interaction of hydrogen with metal nitrides and imides [J].

Chen, P ;

Xiong, ZT ;

Luo, JZ ;

Lin, JY ;

Tan, KL .

NATURE, 2002, 420 (6913) :302-304

[8] Pd nanoparticles supported on MIL-101 as high-performance catalysts for catalytic hydrolysis of ammonia borane [J].

Dai, Hongmei ;

Su, Jun ;

Hu, Kai ;

Luo, Wei ;

Cheng, Gongzhen .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (10) :4947-4953

[9] Hydrogen storage: beyond conventional methods [J].

Dalebrook, Andrew F. ;

Gan, Weijia ;

Grasemann, Martin ;

Moret, Severine ;

Laurenczy, Gabor .

CHEMICAL COMMUNICATIONS, 2013, 49 (78) :8735-8751

[10] Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101 [J].

El-Shall, M. Samy ;

Abdelsayed, Victor ;

Khder, Abd El Rahman S. ;

Hassan, Hassan M. A. ;

El-Kaderi, Hani M. ;

Reich, Thomas E. .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (41) :7625-7631

← 1 2 3 4 5 6 7 →