Al-Ti2O6 a mixed metal oxide based composite membrane: A unique membrane for removal of heavy metals

被引:88
作者
Sunil, Kalakonnavar [1 ]
Karunakaran, Gopalu [2 ,3 ]
Yadav, Sudesh [1 ]
Padaki, Mahesh [1 ]
Zadorozhnyy, Vladislav [4 ]
Pai, Ranjith Krishna [5 ]
机构
[1] Jain Univ, Ctr Nano & Mat Sci, Jain Global Campus, Bangalore 562112, Karnataka, India
[2] Natl Univ Sci & Technol, Dept Funct Nanosyst & High Temp Mat, MISiS, Leninskiy Pr 4, Moscow 119049, Russia
[3] KS Rangasamy Coll Arts & Sci Autonomous, Dept Biotechnol, Tiruchengode 637215, Tamil Nadu, India
[4] Natl Univ Sci & Technol, MISiS, Leninskiy Pr 4, Moscow 119049, Russia
[5] Govt India, Minist Sci & Technol, Dept Sci & Technol DST, Technol Mission Div,Technol Bhavan, New Mehrauli Rd, New Delhi 110016, India
基金
奥地利科学基金会;
关键词
Mixed matrix membranes; Surface roughness; Hydrophilicity; Heavy metal rejection; WATER-TREATMENT; OSMOSIS PROCESS; WASTE-WATER; IONS; REJECTION; NANOFILTRATION; POLYSULFONE; NANOPARTICLES; DESALINATION; PERFORMANCE;
D O I
10.1016/j.cej.2018.05.017
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the current study, a novel Al-Ti2O6 nanoparticles and polysulfone composite membranes were prepared and used for the removal of heavy metal ions. Al-Ti2O6 was prepared by precipitation method and the membranes were prepared by diffusion induced phase separation method with different compositions of Al-Ti2O6. The prepared Al-Ti2O6 nanoparticle was confirmed by XRD, and SEM analysis. However, FE-SEM was used to confirm the presence of nanoparticles in the membrane. EDX and elemental mapping were performed to confirm uniform distribution of nanoparticles in the membranes. The hydrophilicity of the membrane was measured by contact angle, water uptake and water flux study and it was increased with respect to increasing concentration of nanoparticles. Performance of the membrane was analyzed by rejection of heavy metals such as As, Cd, and Pb. The membrane was showed rejection percentage of about 96% for As, 98% for Cd and 99% for Pb. The concentration of nanoparticles and filtration time was investigated in detail. The obtained results prove Al-Ti2O6 a mixed metal oxide composite membrane a potential candidate for the removal of As, Cd, and Pb.
引用
收藏
页码:678 / 684
页数:7
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