Study on thermodynamic properties of polyelectrolyte solutions

被引：0

作者：

Feng, Z ^{[1
]}

Liu, HL ^{[1
]}

Hu, Y ^{[1
]}

机构：

[1] E CHINA UNIV SCI & TECHNOL,DEPT CHEM,SHANGHAI 200237,PEOPLES R CHINA

来源：

ACTA CHIMICA SINICA | 1996年 / 54卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on a cylindrical cell model and Vink's approximation, distributions of electric potential around polyion under various conditions are obtained by solving Poisson-Boltzmann equation. Activity coefficients of polyion, counterion and coion are calculated from those potential distribution. Osmotic coefficients of solvent are also obtained. Predicted mean-activity coefficients of simple salts added for systems of NaPP-NaCl, NaPP-NaBr and NaCarr-NaI are in good agreement with the experimental results.

引用

页码：1076 / 1083

页数：8

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