Removal of azo and anthraquinone reactive dyes from industrial wastewaters using MgO nanoparticles

In the present investigation, a porous MgO powder was synthesized and tested for the removal of dyes from aqueous solution. The size of the MgO particles was in the range of 38-44 nm, with an average specific surface area of 153.7 m(2)/g. Adsorption of reactive blue 19 and reactive red 198 was conducted to model azo and anthraquinone dyes at various MgO dosages, dye concentrations, solution pHs and contact times in a batch reactor. Experimental results indicate that the prepared MgO powder can remove more than 98% of both dyes under optimum operational conditions of a dosage of 0.2 g. pH 8 and a contact time of 5 min for initial dye concentrations of 50-300 mg/L. The isotherm evaluations revealed that the Langmuir model attained better fits to the experimental equilibrium data than the Freundlich model. The. maximum predicted adsorption capacities were 166.7 and 123.5 mg of dye per grain of adsorbent for RB 19 and RR 198, respectively. In addition, adsorption kinetic data followed a pseudo-second-order rate for both tested dyes. (C) 2009 Elsevier B.V. All rights reserved