Preparation of Ag2SO3 sub-microparticles with high visible-light photocatalytic activity

被引:10
作者
Dong, Chao [1 ]
Wu, Kong-Lin [1 ]
Wei, Xian-Wen [1 ,2 ]
Wang, Jing [1 ]
Liu, Li [1 ]
Hu, Yu [1 ]
Xia, Shan-Hui [1 ]
机构
[1] Anhui Normal Univ, Coll Chem & Mat Sci, Anhui Lab Mol Based Mat, Anhui Key Lab Funct Mol Solids,Minist Educ, Wuhu 241000, Peoples R China
[2] Anhui Univ Technol, Sch Chem & Engn, Key Lab Funct Mol Solids, Maanshan 243002, Peoples R China
关键词
REACTION-MECHANISM; ORGANIC-COMPOUNDS; RHODAMINE-B; DEGRADATION; EFFICIENT; PHOTOOXIDATION; NANOCOMPOSITES; SEMICONDUCTOR; AGSBO3; AGCL;
D O I
10.1049/mnl.2014.0110
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A visible-light sensitive Ag2SO3 semiconductor photocatalyst with size of ca. 500 nm was prepared by a simple precipitation method. This photocatalyst exhibits high-efficiency degradation ability for typical three dyes, which can be ascribed to the efficient photosensitised electron injection and slow electron recombination. The photocatalytic reaction follows a pseudo-first-order reaction and the rate constant of Ag2SO3 for the degradation of rhodamine B is estimated to be 1.7 times that of commercial TiO2. The stability of unstable Ag2SO3 was remarkably enhanced by the addition of Na2SO3. The h(+) and center dot O-2(-) played relatively major roles during the photocatalytic reaction.
引用
收藏
页码:417 / 420
页数:4
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