Guest-induced conformational switching in a single crystal

被引：87

作者：

Dobrzanska, Liliana ^{[1
]}

Lloyd, Gareth O. ^{[1
]}

Esterhuysen, Catharine ^{[1
]}

Barbour, Leonard J. ^{[1
]}

机构：

[1] Univ Stellenbosch, Dept Chem, ZA-7602 Matieland, South Africa

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 35期

关键词：

cooperative phenomena; crystal engineering; host-guest systems; phase transitions; solvatochromism;

D O I：

10.1002/anie.200602057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Without destruction of monocrystallinity: The conformational switching of a dinuclear metal complex between four distinct states (see picture) occurs without destroying the single crystal. This observation implies a substantial degree of cooperativity between host molecules during guest uptake, release, or exchange. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5856 / 5859

页数：4

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