Chiral salen manganese complex encapsulated within zeolite Y: A heterogeneous enantioselective catalyst for the epoxidation of alkenes

被引：245

作者：

Sabater, MJ ^{[1
]}

Corma, A ^{[1
]}

Domenech, A ^{[1
]}

Fornes, V ^{[1
]}

Garcia, H ^{[1
]}

机构：

[1] UNIV POLITECN VALENCIA, CSIC, INST TECNOL QUIM, VALENCIA 46071, SPAIN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 14期

关键词：

D O I：

10.1039/a701337j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral (salen)Mn-III complex [salen: trans-(R,R)-1,2-bis(salicylideneamino)cyclohexane] analogous to Jacobsen's catalyst is prepared inside the supercages of zeolite Y, showing catalytic activity very similar to that of the chloride complex in the homogeneous phase.

引用

页码：1285 / 1286

页数：2

共 11 条

[1] INFLUENCE OF THE SOLVENT ON THE TITANIUM-BETA CATALYZED OXIDATION OF PHENYLETHYLENES WITHOUT CARBON-CARBON DOUBLE-BOND CLEAVAGE [J].

ALVARO, M ;

CORMA, A ;

GARCIA, H ;

VALENCIA, S .

APPLIED CATALYSIS A-GENERAL, 1995, 128 (01) :L7-L11

[2] Zeolite-modified electrodes: Intra- versus extrazeolite electron transfer - Comment [J].

Bedioui, F ;

Devynck, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (20) :8607-8609

[3] THE SYNTHETIC METHODOLOGY OF NONRACEMIC GLYCIDOL AND RELATED 2,3-EPOXY ALCOHOLS [J].

HANSON, RM .

CHEMICAL REVIEWS, 1991, 91 (04) :437-475

[4] ELECTRONIC TUNING OF ASYMMETRIC CATALYSTS [J].

JACOBSEN, EN ;

ZHANG, W ;

GULER, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (17) :6703-6704

[5] HIGHLY ENANTIOSELECTIVE EPOXIDATION CATALYSTS DERIVED FROM 1,2-DIAMINOCYCLOHEXANE [J].

JACOBSEN, EN ;

ZHANG, W ;

MUCI, AR ;

ECKER, JR ;

DENG, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7063-7064

[6] THE 1ST PRACTICAL METHOD FOR ASYMMETRIC EPOXIDATION [J].

KATSUKI, T ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) :5974-5976

[7]

Lucas H J., 1955, ORG SYNTH, V3, P483

[8] Polymer-bound chiral (salen)Mn(III) complex as heterogeneous catalyst in rapid and clean enantioselective epoxidation of unfunctionalised olefins [J].

Minutolo, F ;

Pini, D ;

Salvadori, P .

TETRAHEDRON LETTERS, 1996, 37 (19) :3375-3378

[9]

Morrison J. D., 1983, ASYMMETRIC SYNTHESIS

[10]

VENKELECOM IEJ, 1996, ANGEW CHEM INT EDIT, V35, P1346

← 1 2 →