Ex-situ Antimony Screen-printed Carbon Electrode for Voltammetric Determination of Ni(II)-ions in Wastewater

被引：19
作者：
Barcelo, Cristian [1 ]
Serrano, Nuria [1 ]
Arino, Cristina [1 ]
Manuel Diaz-Cruz, Jose [1 ]
Esteban, Miquel [1 ]
机构：
[1] Univ Barcelona, Fac Quim, Dept Quim Analit, Marti i Franques 1-11, E-08028 Barcelona, Spain
来源：
ELECTROANALYSIS | 2016年 / 28卷 / 03期
关键词：
antimony film electrodes; screen-printed electrodes; adsorptive stripping voltammetry; nickel; ADSORPTIVE STRIPPING VOLTAMMETRY; BISMUTH FILM ELECTRODES; HEAVY-METAL IONS; TRACE NICKEL; IN-SITU; CD(II); PB(II); CU(II);
D O I：
10.1002/elan.201500511
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An Ex-situ antimony film screen-printed carbon electrode (Ex-situ SbSPCE) was successfully applied for the determination of Ni(II), by means of adsorptive stripping voltammetry using dimethylglyoxime as complexing agent, in a certified reference wastewater sample. This electrode is proposed as an alternative to more conventional antimony film electrodes. Ex-situ SbSPCE was analytically characterized and the obtained parameters suggest that Ex-situ SbSPCE behaves much better than both Ex-situ BiSPCE and BispSPE for Ni(II) determination. The results confirm the applicability of Ex-situ SbSPCE for the determination of low concentration levels of Ni(II) in natural samples with a very high reproducibility and good trueness.
引用
收藏
页码：640 / 644
页数：5
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