Iron-based perovskites LaFe0.5M0.5O3, with the orthorhombic (S.G. Pbnm) and rhombohedral (S.G. R-3c) structure for M=Co and Ni, respectively were synthesized using the sol-gel method, in contrast to the literature results. Magnetic investigations reveal that LaFe0.5Co0.5O3 is a canted antiferromagnet and reaches a magnetic transition of 370 K, i.e., much above the 300 K value observed by previous authors, whereas LaFe0.5Ni0.5O3 is antiferromagnetic at low temperature. [GRAPHICS] . The sol-gel synthesized LaFe0.5Co0.5O3 perovskite to be stabilized at room temperature with a pure orthorhombic phase. The magnetization behavior reveals the perovskite is canted antiferromagnet at low temperature.
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Bharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, IndiaBharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, India
Nithya, V. D.
Immanuel, R. Jacob
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Bharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, IndiaBharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, India
Immanuel, R. Jacob
Senthilkumar, S. T.
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Bharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, IndiaBharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, India
Senthilkumar, S. T.
Sanjeeviraja, C.
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Alagappa Univ, Sch Phys, Karaikkudi 630003, Tamil Nadu, IndiaBharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, India
Sanjeeviraja, C.
Perelshtein, I.
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Bar Ilan Univ, Dept Chem, Bar Ilan Inst Nanotechnol & Adv Mat, IL-52900 Ramat Gan, IsraelBharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, India
Perelshtein, I.
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Zitoun, D.
Selvan, R. Kalai
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Bharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, IndiaBharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, India