Organogelators based on p-alkoxylbenzamide and their self-assembling properties

被引：5
作者：
Zhai, Yan [1 ]
Chai, Wei [1 ]
Cao, Wenwen [1 ]
Sun, Zipei [1 ]
Huang, Yaodong [1 ]
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Syst Bioengn, Tianjin 300072, Peoples R China
来源：
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING | 2015年 / 9卷 / 04期
关键词：
p-alkoxylbenzamide; organogelator; self-assembly; gelation; GELATORS; GELATION; ANION;
D O I：
10.1007/s11705-015-1503-9
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A series of p-alkoxylbenzamides featuring a long alkyl chain have been synthesized and are readily to form stable gels in a variety of organic solvents. Their self-assembly properties and structure-property relationship were investigated by scanning electron microscopy, X-ray diffraction, H-1 nuclear magnetic resonance, and Fourier transform infrared spectroscopy. The gels formed were multi-responsive to environmental stimuli such as temperature and fluoride anion. The results show that a combination of hydrogen bonding, pi-pi stacking and van der Waals interaction result in the aggregation of p-alkoxylbenzamides to form three-dimension networks, depending on the length of the long alkyl chain.
引用
收藏
页码：488 / 493
页数：6
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