Synthesis and characterization of some new transition metal complexes of the Schiff base derived from quinoxaline-2-carboxaldehyde and 2-aminophenol

被引：16

作者：

Mayadevi, S ^{[1
]}

Yusuff, KKM ^{[1
]}

机构：

[1] COCHIN UNIV SCI & TECHNOL,DEPT APPL CHEM,COCHIN 682022,KERALA,INDIA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 02期

关键词：

HETEROCYCLIC NITROGEN; COPPER(II); KETONES;

D O I：

10.1080/00945719708000155

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some new transition metal complexes of the Schiff base quinoxaline-2-carboxalidene-2-aminophenol (HQAP) have been synthesized and characterized by elemental analyses, conductance and magnetic measurements and IR and UV-Visible spectral studies. The complexes have the following empirical formulae: [Mn(QAP)(2)], [Fe(QAP)(2)Cl], [Co(QAP)(2)], [Ni(QAP)(2)] and [Cu(QAP)(2)]. A tetrahedral structure has been assigned for the manganese(II), cobalt(II), nickel(II) and copper(II) complexes. For the iron(III) complex an octahedral dimeric structure has been suggested.

引用

页码：319 / 330

页数：12

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