Improved Photocatalytic Activity of g-C3N4/ZnO: A PotentialDirect Z-Scheme Nanocomposite

被引:32
作者
Ramachandra, Madhushree [1 ]
Devi Kalathiparambil Rajendra Pai, Sunaja [1 ]
Resnik Jaleel UC, Jadan [1 ]
Pinheiro, Dephan [1 ]
机构
[1] CHRIST Deemed Univ, Dept Chem, Hosur Rd, Bengaluru 560029, Karnataka, India
来源
CHEMISTRYSELECT | 2020年 / 5卷 / 38期
关键词
Energy conversion; g-C3N4; ZnO; Malachite green degradation; Nanocomposite; Z-scheme photocatalysis; GRAPHITIC CARBON NITRIDE; MALACHITE GREEN; CO2; REDUCTION; ZNO; DYE; PHOTODEGRADATION; DEGRADATION; FABRICATION; NANOSHEETS; COMPOSITE;
D O I
10.1002/slct.202003166
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, a Z-scheme g-C3N4/ZnO nanocomposite was synthesized using exfoliation process, which was further characterized using XRD, FT-IR, UV-DRS, SEM-EDAX, PL, EIS, and TGA techniques. The properties of g-C(3)N(4)were enhanced when fabricated with ZnO resulting in a better electron mobility, high redox potential, and excellent semiconducting properties. The performance of this heterostructure was evaluated by photocatalytic degradation of malachite green (MG) under visible light irradiation. The g-C3N4/ZnO heterostructure achieved a degradation of 84.3 % within 60 min under visible light irradiation. The degradation reaction follows a pseudo first-order kinetic model with a reaction rate constant of 0.0329 min(-1). The nanocomposite demonstrated outstanding stability and recyclability.
引用
收藏
页码:11986 / 11995
页数:10
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