Electropolymerization of palladium tetraaminephthalocyanine: Characterization and supercapacitance behavior

被引：31

作者：

Lokesh, Koodlur Sannegowda ^{[1
]}

Adriaens, Annemie ^{[2
]}

机构：

[1] Vijayanagara Sri Krishnadevaraya Univ, Dept Chem, Bellary 58310, Karnataka, India

[2] Univ Ghent, Dept Analyt Chem, B-9000 Ghent, Belgium

来源：

DYES AND PIGMENTS | 2015年 / 112卷

关键词：

Electropolymerization; Poly(PdTAPc); EIS; Supercapacitor; Phthalocyanine; CV; ALCOHOL OXIDATION; REDOX PROPERTIES; THIN-FILMS; PHTHALOCYANINE; GOLD; CORROSION; CARBON; AFM; METALLOPHTHALOCYANINES; ELECTROOXIDATION;

D O I：

10.1016/j.dyepig.2014.06.034

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The formation of a supramolecular electropolymerized film of a polymeric palladium phthalocyanine on a glassy carbon electrode is reported here. The film was obtained by cycling monomeric palladium tetraaminephthalocyanine in dimethyl sulfoxide in the potential range -0.5 to +1.0 V. The functionalized polymerized film on the electrode was characterized using Raman spectroscopy, X-ray photoelectron spectroscopy and electrochemical methods. A polymeric phthalocyanine film was shown to form by the oxidation of peripheral amino groups. It uniformly and completely covered the electrode surface. The modified electrode surface slightly blocked the reversible redox behavior of a redox probe owing to the thick polymeric film on its surface. The modified electrode showed a redox capacitance of 146 F g(-1) at 0.27 V in 0.5 M sulfuric acid. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：192 / 200

页数：9

共 46 条

[1] Studies on tetra-amine phthalocyanines [J].

Achar, BN ;

Lokesh, KS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (21) :3357-3361

[2] Studies on phthalocyanine sheet polymers [J].

Achar, BN ;

Lokesh, KS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (16) :2601-2605

[3] Voltammetric characterisation of the self-assembled monolayers (SAMs) of benzyl- and dodecyl-mercapto tetra substituted metallophthalocyanines complexes [J].

Agboola, Bolade ;

Westbroek, Philippe ;

Ozoemena, Kenneth I. ;

Nyokong, Tebello .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (02) :310-316

[4] Comparative electrooxidation of nitrite by electrodeposited Co(II), Fe(II) and Mn(III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines on gold electrodes [J].

Agboola, Bolade ;

Nyokong, Tebello .

ANALYTICA CHIMICA ACTA, 2007, 587 (01) :116-123

[5]

Alpatova NM, 2010, ELECTROPOLYMERIZATIO, P296

[6] Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells [J].

Bianchini, Claudio ;

Shen, Pei Kang .

CHEMICAL REVIEWS, 2009, 109 (09) :4183-4206

[7] The determination of the thickness of electrodeposited polymeric films by AFM and electrochemical techniques [J].

Bienkowski, Krzysztof ;

Strawski, Marcin ;

Szklarczyk, Marek .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2011, 662 (01) :196-203

[8]

Bruti EM, 1999, ELECTROANAL, V11, P565, DOI 10.1002/(SICI)1521-4109(199906)11:8<565::AID-ELAN565>3.0.CO

[9]

2-V

[10] Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors [J].

Chidembo, Alfred T. ;

Ozoemena, Kenneth I. ;

Agboola, Bolade O. ;

Gupta, Vinay ;

Wildgoose, Gregory G. ;

Compton, Richard G. .

ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (02) :228-236

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