Rotationally resolved infrared absorption spectrum of N-4(+)

被引：46
|
作者：
Ruchti, T [1 ]
Speck, T [1 ]
Connelly, JP [1 ]
Bieske, EJ [1 ]
Linnartz, H [1 ]
Maier, JP [1 ]
机构：
[1] UNIV BASEL,INST PHYS CHEM,CH-4056 BASEL,SWITZERLAND
来源：
JOURNAL OF CHEMICAL PHYSICS | 1996年 / 105卷 / 07期
关键词：
D O I：
10.1063/1.472124
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rotationally resolved infrared band of the antisymmetric stretching vibration (nu(3)) of N-4(+) has been recorded by tunable diode laser spectroscopy. A continuous supersonic expansion of pure nitrogen through a slit nozzle and electron impact ionization was employed. Forty-four P and R branch transitions with J up to 25 are observed. The band origin is at nu(0)=2234.5084(4) cm(-1) and the rotational constants are determined to be B-0=0.112 05(3) cm(-1) and B-1=0.111 76(3) cm(-1). The infrared spectrum shows that N-4+ has a linear ground state structure. (C) 1996 American Institute of Physics.
引用
收藏
页码：2591 / 2594
页数：4
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