Effects of Metal Ions and N-Donor Ligands with Different Coordination Characters on the Construction of d10 Metal-organic Complexes with Selective Photocatalytic Activities

被引:0
作者
Liu, Guo-Cheng [1 ]
Chen, Nai-Li [1 ]
Zhang, Ju-Wen [1 ]
Qu, Yun [1 ]
Lin, Hong-Yan [1 ]
Gao, Xin-Jie [1 ]
机构
[1] Bohai Univ, Dept Chem, Liaoning Prov Silicon Mat Engn Technol Res Ctr, Jinzhou 121000, Peoples R China
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2014年 / 69卷 / 06期
基金
中国国家自然科学基金;
关键词
Hydrothermal Syntheses; Crystal Structures; d(10) Metal-organic Coordination Polymers; Photoluminescence; Photocatalytic Activities; 2-D LAYERED NETWORK; BIS-AMIDE LIGANDS; CRYSTAL-STRUCTURES; MIXED-LIGANDS; METALORGANIC FRAMEWORKS; COMPOSITE-MATERIAL; POLYMERS; DICARBOXYLATES; ARCHITECTURES; FABRICATION;
D O I
10.5560/ZNB.2014-3326
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Four new d(10) metal-organic coordination polymers, [Zn(L)(phen)(H2O)] (1), [Cd(L)(phen)] (2), [Zn(L)(bppdc)]center dot 3H(2)O (3), and [Cd(L)(bppdc)]center dot 3H(2)O (4) [L = 2-carboxymethylsulfanyl nicotinic acid, phen = 1,10-phenanthroline, bppdc = N,N'-bis(pyridin-3-yppyridine-2,6-dicarboxamide], have been obtained from hydrothermal reactions of zinc(II)/cadmium(H) nitrates with the semi-rigid N-/ S-containing dicarboxylate L, and the two structurally disparate neutral N-donor ligands phen and bppdc. Single-crystal X-ray diffraction analysis has revealed that compound 1 is a one-dimensional (1-D) helical coordination polymer linked by Zn-II atoms and L spacers. Compound 2 features a double-chain structure connected via binuclear Cd-II units and pairs of L linkers. Adjacent chains of 1 and 2 are packed into 3-D supramolecular networks by hydrogen bonds and pi-pi stacking interactions. Compounds 3 and 4 exhibit similar 2-D (4,4)-connected wave-like networks based on linear [M-L], and zigzag [M-bppdc](n) metal-organic chains (M = Zn-II for 3 and Cd-II for 4). The effects of metal ions and N-donor ligands with different coordination characters are discussed. Moreover, the photoluminescence properties and photocatalytic activities of compounds 1-4 were investigated.
引用
收藏
页码:681 / 690
页数:10
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