Synthesis and crystal structure of the coordination compounds of Cd(II) and Zn(II) transition-metal nitrates with acetamide

被引：0

作者：

Palkina, KK ^{[1
]}

Kuz'mina, NE ^{[1
]}

Orlova, VT ^{[1
]}

Smolentsev, AY ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 47卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds Cd(NO3)(2) (.) 6(CH3CONH2) (.) 2H(2)O (1) and Zn(NO3)(2)-6(CH3CONH2) (.) 2H(2)O (II) were synthesized and studied by X-ray crystallography. The crystals of I and II are isostructural and belong to the triclinic system: space group P (1) over bar, Z = 1; a = 7.349(4) and 7.259(5) Angstrom, b = 9.288(4) and 9.289(4) Angstrom, c 10.878(7) and 10.781(7) Angstrom; alpha = 80.98(4)degrees and 80.30(5)degrees, beta = 74.13(5)degrees and 74.07(6)degrees, y = 72.74(4)degrees and 72.88degrees, V = 679.7(5) and 665.0(5) Angstrom(3); rho(calcd) = 1.534 and 1.448 g/cm(3) for I and II, respectively. These compounds are promising as plant-growth stimulators.

引用

页码：841 / 846

页数：6

共 9 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[2] Antsyshkina AS, 1997, ZH NEORG KHIM+, V42, P1468
[3] KOSTERINA VI, 1985, THESIS USSR ACAD SCI
[4] ORLOVA VT, 1985, ZH NEORG KHIM+, V30, P1877
[5] ORLOVA VT, 1991, Patent No. 1639453
[6] Palkina K.K., 1999, ZH NEORG KHIM, V44, P963
[7] Palkina KK, 1996, ZH NEORG KHIM+, V41, P1656
[8] PALKINA KK, 1995, ZH NEORG KHIM+, V40, P1150
[9] SHELDRICK GM, 1993, SHELX93 PROGRAM REFI

← 1 →