A new non-centrosymmetric modification of BiB3O6

被引：90

作者：

Knyrim, Johanna S.

Becker, Petra

Johrendt, Dirk

Huppertz, Hubert

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

[2] Univ Cologne, Inst Kristallog, D-50674 Cologne, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期

关键词：

bismuth triborate; borates; high-pressure chemistry; nonlinear optics; solid-state structures;

D O I：

10.1002/anie.200602993

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Working under pressure: BiB3O6 is a well-known material with nonlinear optical properties. The use of high-pressure/high- temperature conditions led to the synthesis of a new non-centrosymmetric bismuth triborate (δ-BiB3O6). The picture shows a six-membered ring in the crystal structure of δ-BiB3O 6 (orange spheres: Bi, blue spheres: O, red spheres: B). (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：8239 / 8241

页数：3

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