Microstructure and high-temperature oxidation resistance of MoSi2-ZrO2 composite coatings for Niobium substrate

被引：41
作者：
Zhu, Lu [1 ,2 ]
Ren, Xuanru [1 ]
Wang, Xiaohong [1 ]
Kang, Xueqin [1 ]
Zheng, Ruixin [1 ]
Feng, Peizhong [1 ]
机构：
[1] China Univ Min & Technol, Sch Mat Sci & Engn, Xuzhou 221116, Jiangsu, Peoples R China
[2] China Univ Min & Technol, Sch Chem Engn & Technol, Xuzhou 221116, Jiangsu, Peoples R China
来源：
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2021年 / 41卷 / 02期
基金：
中国国家自然科学基金;
关键词：
spent MoSi2; ZrO2; oxidation behavior; Niobium substrate; spark plasma sintering; MECHANICAL-PROPERTIES; C/C COMPOSITES; MOSI2-BASED COMPOSITE; THERMAL-EXPANSION; SPRAYED MOSI2; BEHAVIOR; ALLOY; PROTECTION; EVOLUTION; PHASE;
D O I：
10.1016/j.jeurceramsoc.2020.09.029
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Spent MoSi2 heating elements, which worked in the industrial electrical furnace at high temperature, were crushed into powders and reused as coating raw materials. ZrO2 was added into spent MoSi2 powders to fabricate MoSi2-ZrO2 coatings on niobium by spark plasma sintering, and the microstructure and oxidation behavior of the coatings at 1500 and 1700 degrees C were explored. The results showed that cracks exist in MoSi2 coating while ZrO2 containing coatings are crack-free with the formation of (Mo,Nb)(5)Si-3 diffusion layer after SPS, indicating good metallurgical bonding. After oxidation at 1500 degrees C for 20 h, the lowest mass gain is obtained by MoSi2-30ZrO(2) coating. SiO2 and ZrSiO4 are formed on the composite coatings at elevated temperature, which improves the high-temperature oxidation resistance. After oxidation at 1700 degrees C for 60 min, the oxide scale of MoSi2-30ZrO(2) coating is dense without any voids or cracks, demonstrating better high-temperature oxidation resistance than that of single MoSi2 coating.
引用
收藏
页码：1197 / 1210
页数：14
相关论文
共 81 条
[41]   Oxidation of MoSi2 and MoSi2-based materials [J].
Ramasesha, SK ;
Shobu, K .
BULLETIN OF MATERIALS SCIENCE, 1999, 22 (04) :769-773
[42]   Comparative studies of the oxidation of MoSi2 based materials: Low-temperature oxidation (300-900 °C) [J].
Samadzadeh, M. ;
Oprea, C. ;
Sharif, H. Karimi ;
Troczynski, T. .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2017, 66 :11-20
[43]   Development of coatings for protection in specific high temperature environments [J].
Schuetze, M. ;
Malessa, M. ;
Rohr, V. ;
Weber, T. .
SURFACE & COATINGS TECHNOLOGY, 2006, 201 (07) :3872-3879
[44]   Oxidation behaviour of a pressureless sintered AlN-SiC composite [J].
Sciti, D ;
Winterhalter, F ;
Bellosi, A .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (23) :6965-6973
[45]   Studies on the surface chemistry of oxide films formed on IN-738LC superalloy at elevated temperatures in dry air [J].
Seal, S ;
Kuiry, SC ;
Bracho, LA .
OXIDATION OF METALS, 2001, 56 (5-6) :583-603
[46]   Preparation of TZM alloy by aluminothermic smelting and its characterization [J].
Sharma, IG ;
Chakraborty, SP ;
Suri, AK .
JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 393 (1-2) :122-128
[47]   Microstructure of NbSi2/SiC nanocomposite coating formed on Nb substrate [J].
Son, KH ;
Yoon, JK ;
Han, JH ;
Kim, GH ;
Doh, JM ;
Lee, SR .
JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 395 (1-2) :185-191
[48]   Effect of thermodynamically metastable components on mechanical and oxidation properties of the thermal-sprayed MoSi2 based composite coating [J].
Sun, Jia ;
Li, Tao ;
Zhang, Guang-Peng .
CORROSION SCIENCE, 2019, 155 :146-154
[49]   Oxidation response determined by multiphase-dependent melting degree of plasma sprayed MoSi2 on Nb-based alloy [J].
Sun, Jia ;
Fu, Qian-Gang ;
Huo, Cai-Xia ;
Li, Tao ;
Wang, Chen ;
Cheng, Chun-Yu ;
Yang, Guan-Jun ;
Sun, Jia-Cong .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 762 :922-932
[50]   A MoSi2-based composite coating by supersonic atmospheric plasma spraying to protect Nb alloy against oxidation at 1500 °C [J].
Sun, Le ;
Fu, Qian-Gang ;
Fang, Xiang-Qing ;
Sun, Jia .
SURFACE & COATINGS TECHNOLOGY, 2018, 352 :182-190
123456789