Synthesis and characterisation of Fe,Co-mixed metal polynuclear complexes with C4H and C4 ligands derived from butadiynyl (X = H) and butadiynediyl iron complexes (X = Fp), Fp-CC-CC-X [Fp* = (η5-C5Me5)Fe(CO)2]:: Transformation of the C4(H) cluster frameworks via valence isomerization and 1,2-H shift of the carbon linkages

被引：37

作者：

Chung, MC ^{[1
]}

Sakurai, A ^{[1
]}

Akita, M ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 23期

关键词：

D O I：

10.1021/om990494c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sequential addition of Co-2(CO)(8) and Fe-2(CO)(9) to Fp*-C equivalent to C-C equivalent to C-X (X = H (1), Fp* (2)) affords a variety of Fe,Co mixed metal cluster compounds resulting from a combination of (1) addition of a Co-2 fragment to the C equivalent to C bonds, (2) reorganization of the cluster framework including metal-metal bond formation, (3) replacement of metal fragments and transfer of metal fragments, (4) valence isomerization of the C-4(H) Linkage, and (5) 1,2-H shift of the C4H ligand.

引用

页码：4684 / 4691

页数：8

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