Removal of toxic metal ions with magnetic hydrogels

被引:361
作者
Ozay, Ozgur [1 ]
Ekici, Sema [1 ]
Baran, Yakup [1 ]
Aktas, Nahit [2 ]
Sahiner, Nurettin [1 ]
机构
[1] Canakkale Onsekiz Mart Univ, Fac Sci & Arts, Dept Chem, Nanomat & Nanotechnol Res Lab, TR-17020 Canakkale, Turkey
[2] Yuzuncu Yil Univ, Fac Engn & Architecture, Dept Chem Engn, TR-65080 Van, Turkey
关键词
Remediation; Magnetic; Composite; Functional hydrogel; Pollution; AQUEOUS-SOLUTION; POLYMER NETWORKS; LEAD IONS; ADSORPTION; ACID; NANOCOMPOSITES; NANOPARTICLES; MICROSPHERES; COPPER; IRRADIATION;
D O I
10.1016/j.watres.2009.06.058
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Hydrogels, based on 2-acrylamido-2-methyl-1-propansulfonic acid (AMPS) were synthesized via photopolymerization technique and used for the preparation of magnetic responsive composite hydrogels. These composite hydrogels with magnetic properties were further utilized for the removal of toxic metal ions such as Cd(II), Co(II), Fe(II), Pb(II), Ni(II), Cu(II) and Cr(III) from aqueous environments. It was revealed that hydrogel networks with magnetic properties can effectively be utilized in the removal of pollutants. The results verified that magnetic iron particle containing p(AMPS) hydrogel networks provide advantageous over conventional techniques. Langmuir and Freundlich adsorption isotherms were applied for toxic metal removal and both isotherms were fit reasonably well for the metal ion absorptions. (c) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4403 / 4411
页数:9
相关论文
共 32 条
[1]   Radiation synthesis and characterization of polyamidoamine dendrimer macromolecules with different loads of nickel salt for adsorption of some metal ion [J].
Abou Taleb, Manal F. ;
Elsigeny, Samia M. ;
Ibrahim, Mohamed M. .
RADIATION PHYSICS AND CHEMISTRY, 2007, 76 (10) :1612-1618
[2]   Adsorptive features of chitosan entrapped in polyacrylamide hydrogel for Pb2+, UO22+, and Th4+ [J].
Akkaya, Recep ;
Ulusoy, Ulvi .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 151 (2-3) :380-388
[3]   Competitive heavy metal removal by poly(2-acrylamido-2-methyl-1-propane sulfortic acid-co-itaconic acid) [J].
Cavus, Selva ;
Guerdag, Guelten .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2008, 19 (09) :1209-1217
[4]   Carboxymethylated-bacterial cellulose for copper and lead ion removal [J].
Chen, Shiyan ;
Zou, Yu ;
Yan, Zhiyong ;
Shen, Wei ;
Shi, Shuaike ;
Zhang, Xiang ;
Wang, Huaping .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 161 (2-3) :1355-1359
[5]   Preparation and swelling characterization of poly (n-isopropylacrylamide)-based porous hydrogels [J].
Chern, JM ;
Lee, WF ;
Hsieh, MY .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (06) :3651-3658
[6]   Synthesis and characterization of poly(hydroxyethyl methacrylate-N-methacryloyl-(L)-glutamic acid) copolymer beads for removal of lead ions [J].
Denizli, A ;
Garipcan, B ;
Karabakan, A ;
Senöz, H .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2005, 25 (04) :448-454
[7]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
[8]   Crosslinking Metal Nanoparticles into the Polymer Backbone of Hydrogels Enables Preparation of Soft, Magnetic Field-Driven Actuators with Muscle-Like Flexibility [J].
Fuhrer, Roland ;
Athanassiou, Evogelos Kimon ;
Luechinger, Norman Albert ;
Stark, Wendelin Jan .
SMALL, 2009, 5 (03) :383-388
[9]   Preparation and characterization of poly(2-acrylamido-2-methylpropane-sulfonic acid)/Chitosan hydrogel using gamma irradiation and its application in wastewater treatment [J].
Gad, Y. H. .
RADIATION PHYSICS AND CHEMISTRY, 2008, 77 (09) :1101-1107
[10]   Superabsorbent hydrogrel based on modified polysaccharide for removal of Pb2+ and Cu2+ from water with excellent performance [J].
Guilherme, Marcos R. ;
Reis, Adriano V. ;
Paulino, Alexandre T. ;
Fajardo, Andre R. ;
Muniz, Edvani C. ;
Tambourgi, Elias B. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 105 (05) :2903-2909