Magnetic properties of La0.7Ca0.3MnO3 nanoparticles prepared by reactive milling

被引:19
作者
Manh, Do Hung [1 ]
Thuan, Nguyen Chi [1 ]
Phong, Pham Thanh [2 ]
Van Hong, Le [1 ]
Phuc, Nguyen Xuan [1 ]
机构
[1] Vietnamese Acad Sci & Technol, Inst Mat Sci, Hanoi, Vietnam
[2] Nha Trang Pedag Coll, Nha Trang, Khanh Hoa Prov, Vietnam
关键词
Manganite; La0.7Ca0.3MnO3; Nanoparticles; Magnetic property;
D O I
10.1016/j.jallcom.2009.01.049
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
La0.7Ca0.3MnO3 (LCMO) nanoparticles were synthesized by reactive milling in ambient conditions. Magnetic properties of LCMO single-phase nanocrystalline particles were studied. LCMO nanoparticles exhibit superparamagnetism with blocking temperature that decreases in the logarithmic function as increasing applied magnetic field. Besides, the blocking temperature decreases as increasing milling time from 8 h to 16 h. The temperature dependence of the saturation magnetization shows a strong collective excitation due to the spin wave that depends on temperature in form T-alpha with alpha = 1.7, which slightly deviates from the Bloch law. (c) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:828 / 831
页数:4
相关论文
共 9 条
[1]   Anomalous properties of magnetic nanoparticles [J].
Berkowitz, AE ;
Kodama, RH ;
Makhlouf, SA ;
Parker, FT ;
Spada, FE ;
McNiff, EJ ;
Foner, S .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 196 :591-594
[2]  
Del Bianco L, 2005, NAN SCI TEC, P217
[3]   Superparamagnetism and transport properties of ultrafine La2/3Ca1/3MnO3 powders [J].
Li, RW ;
Xiong, H ;
Sun, JR ;
Li, QA ;
Wang, ZH ;
Zhang, J ;
Shen, BG .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2001, 13 (01) :141-148
[4]   Deviation from Bloch T3/2 law in ferrite nanoparticles [J].
Mandal, K. ;
Mitra, Subarna ;
Kumar, P. Anil .
EUROPHYSICS LETTERS, 2006, 75 (04) :618-623
[5]   Interacting superparamagnetism in La0.7Sr0.3MnO3 nanoparticles [J].
Nguyen, Ha M. ;
Manh, D. H. ;
Hong, L. V. ;
Phuc, N. X. ;
Yao, Y. D. .
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2008, 52 (05) :1447-1451
[6]   Perovskite nanoparticles: Preparation by reactive milling and magnetic characteristics [J].
Phuc, NX ;
Nguyen, HM ;
Manh, DH ;
Hung, LT ;
Tuong, LTC ;
Hong, LV ;
Yao, YD .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2006, 304 (01) :133-137
[7]   Size induced variations in structural and magnetic properties of double exchange La0.8Sr0.2MnO3-δ nano-ferromagnet [J].
Roy, S ;
Dubenko, I ;
Edorh, DD ;
Ali, N .
JOURNAL OF APPLIED PHYSICS, 2004, 96 (02) :1202-1208
[8]  
*SIEMENS, 1994, PROF US GUID
[9]   Synthesis of single-crystalline perovskite barium titanate nanorods by a combined route based on sol-gel and surfactant-templated methods [J].
Zhang, Shuyan ;
Jiang, Fusong ;
Qu, Gang ;
Lin, Congyi .
MATERIALS LETTERS, 2008, 62 (16) :2225-2228