A hierarchical structured steel mesh decorated with metal organic framework/graphene oxide for high-efficient oil/water separation

被引:138
作者
Li, Hui [1 ,2 ,3 ]
Yin, Yingying [2 ]
Zhu, Lei [1 ,2 ,3 ]
Xiong, Ya [2 ]
Li, Xiao [2 ]
Guo, Tianchao [3 ]
Xing, Wei [2 ]
Xue, Qingzhong [1 ,2 ,3 ]
机构
[1] China Univ Petr, State Key Lab Petr Pollut Control, Qingdao 266555, Shandong, Peoples R China
[2] China Univ Petr, Sch Mat Sci & Engn, Qingdao 266580, Shandong, Peoples R China
[3] China Univ Petr, State Key Lab Heavy Oil Proc, Qingdao 266555, Shandong, Peoples R China
关键词
Metal organic framework; Graphene oxide; Steel mesh; Super-hydrophilic; Oil/water mixture separation; MODIFIED GRAPHENE OXIDE; ADHESIVE SUPEROLEOPHOBICITY; INORGANIC MEMBRANES; GAS SEPARATION; WATER; UIO-66-NH2; SUPERHYDROPHILICITY; FRAMEWORKS; PERFORMANCE; TECHNOLOGY;
D O I
10.1016/j.jhazmat.2019.04.009
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A hierarchical structured steel mesh decorated with metal organic framework (UiO-66-NH2) nanoparticles/graphene oxide (GO) nanosheets was successfully prepared via a simple self-assemble method. Because water molecules tend to build hydrogen bonds with the amine, carboxyl and hydroxyl functional groups of UiO-66-NH2/GO hierarchical structure, the hierarchical structure can easily capture water and tightly lock the water to build a stable water layer on the steel mesh surface and block oil in contact with the steel mesh. Therefore, the obtained hierarchical structured steel mesh exhibits super-hydrophilicity, underwater super-oleophobicity, excellent oil resistance and outstanding oil/water separation performance with a superior high permeating flux (54,500 L m(-2) h(-1)) and rejection (> 99.9%) under gravity force, indicating the mesh possesses great potential for treating oily wastewater.
引用
收藏
页码:725 / 732
页数:8
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