Synthesis of unsymmetrical 1,1′-disubstituted ferrocenes.: Formation of ferrocenophanes via intramolecular cycloaddition

被引:21
作者
Argyropoulos, N [1 ]
Coutouli-Argyropoulou, E [1 ]
机构
[1] Aristotle Univ Thessaloniki, Dept Chem, Organ Chem Lab, GR-54006 Thessaloniki, Greece
关键词
unsymmetrical disubstituted ferrocenes; ferrocenophanes; intramolecular cycloadditions; nitrones;
D O I
10.1016/S0022-328X(02)01394-3
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Unsymmetrical 1,1'-disubstituted ferrocenes bearing appropriate substituents for intramolecular cycloadditions were synthesized conveniently starting from 1,1'-ferrocenedicarbaldehyde. Ferrocenenitrone derivatives reacted in an intramolecular regioselective manner affording ferrocenophanes. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:117 / 122
页数:6
相关论文
共 35 条
[1]   A NEW METHOD FOR STEREOSELECTIVE HOMOALLYLIC AMINE SYNTHESIS [J].
ARMSTRONG, SK ;
COLLINGTON, EW ;
KNIGHT, JG ;
NAYLOR, A ;
WARREN, S .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (13) :1433-1447
[2]   AN IMPROVED SYNTHESIS OF FERROCENE-1,1'-DICARBALDEHYDE [J].
BALAVOINE, GGA ;
DOISNEAU, G ;
FILLEBEENKHAN, T .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) :381-382
[3]   Efficient regio- and diastereo-controlled synthesis of 1,1′- and 1,1′,2,2′-functionalised ferrocenes and the formation of 2-oxa[3]ferrocenophanes [J].
Carroll, MA ;
White, AJP ;
Widdowson, DA ;
Williams, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (10) :1551-1557
[4]  
Chiffre J, 2001, EUR J INORG CHEM, P2221
[5]   Electrochemical studies of ferrocene derivatives and their complexation by β-cyclodextrin [J].
Coutouli-Argyropoulou, E ;
Kelaidopoulou, A ;
Sideris, C ;
Kokkinidis, G .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 477 (02) :130-139
[6]   Formation and cycloaddition reactions of ferrocenyl nitrones [J].
Coutouli-Argyropoulou, E ;
Sabbas, I ;
Konarski, S .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2000, 37 (05) :1055-1060
[7]   1,3-dipolar cycloaddition reactions of isothiazol-3(2H)-ones with nitrile oxides. An unexpected site selectivity of the carbonyl bond of 5-benzoyl-isothiazol-3(2H)-one [J].
CoutouliArgyropoulou, E ;
Anastasopoulos, C .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1996, 33 (03) :731-733
[8]   1,3-DIPOLAR CYCLOADDITION OF NITRILE OXIDES WITH 2-PHENYL-4-ETHOXYMETHYLENE-5(4H)-OXAZOLONE [J].
COUTOULIARGYROPOULOU, E ;
THESSALONIKEOS, E .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1992, 29 (01) :251-253
[9]   Formation and reduction reactions of 3-indol-3-yl-isoxazolidines [J].
CoutouliArgyropoulou, E ;
MalamidouXenikaki, E ;
Stampelos, XN ;
Alexopoulou, IN .
TETRAHEDRON, 1997, 53 (02) :707-718
[10]   A novel method to synthesize asymmetrical disubstituted ferrocenes [J].
Dong, TY ;
Lai, LL .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 509 (02) :131-134