Degradation Kinetics of Polycarbonate Composites: Kinetic Parameters and Artificial Neural Network

被引:21
作者
Charde, S. J. [1 ]
Sonawane, S. S. [1 ]
Sonawane, S. H. [2 ]
Shimpi, N. G. [3 ]
机构
[1] VNIT, Dept Chem Engn, Nagpur 440010, Maharashtra, India
[2] NIT Warangal, Dept Chem Engn, Hanamkonda, Telangana, India
[3] Univ Mumbai, Dept Chem, Bombay, Maharashtra, India
关键词
kinetics; non-isothermal degradation; polycarbonate; Artificial Neural Network; THERMAL-DEGRADATION; TRIBOLOGICAL PROPERTIES; MECHANICAL-PROPERTIES; POLYPROPYLENE; PYROLYSIS; DECOMPOSITION; POLYMERS; HUSK; POLYETHYLENE; PREDICTION;
D O I
10.15255/CABEQ.2017.1173
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
In order to design a reactor, kinetics of degradation of polycarbonate/CaCO3 composites was investigated here by thermogravimetric analysis (TGA), applying model-free and modelistic methods together, to obtain E, A, Delta S*, Delta H* and Delta G* (kinetic parameters). The system was tested with all the mechanisms available using non-isothermal modelistic method (Coats-Redfern). This approach allowed choosing the models, which are otherwise difficult to decide upon simply based on regression fit methods. The mechanism proposed was a simple nth order. Application of artificial neural network supported in designing a neural network could lead to a quick determination of kinetic parameters.
引用
收藏
页码:151 / 165
页数:15
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