Tetrathiafulvalene as an electron acceptor for positive charge induction on the surface of silver nanoparticles for facilitated olefin transport

被引：12

作者：

Choi, Hyungwoo ^{[1
,2
]}

Lee, Jung Hyun ^{[1
,2
]}

Kim, Young Rae ^{[1
,2
]}

Song, Donghoon ^{[1
,2
]}

Kang, Sang Wook ^{[3
]}

Lee, Sang Soo ^{[4
]}

Kang, Yong Soo ^{[1
,2
]}

机构：

[1] Hanyang Univ, Dept Energy Engn, Seoul 133791, South Korea

[2] Hanyang Univ, Ctr Next Generat Dye Sensitized Solar Cells, Seoul 133791, South Korea

[3] Sangmyung Univ, Dept Chem, Seoul 110743, South Korea

[4] Korea Inst Sci & Technol, Photoelect Hybrid Res Ctr, Seoul 136791, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 24期

关键词：

ENERGY-LEVEL ALIGNMENT; ORGANIC/METAL; METAL;

D O I：

10.1039/c3cc48238c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrathiafulvalene (TTF), a well-known electron donor, can also behave as an electron acceptor after being adsorbed on the surface of silver nanoparticles (Ag NPs), thereby inducing a partial positive charge on the Ag NPs surface. The Ag NPs activated by TTF help propylene transport much faster than propane, i.e., facilitated olefin transport, resulting in extremely high separation performance for propylene-propane mixtures.

引用

页码：3194 / 3196

页数：3

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