Enhanced Luminescence of Eu-Doped TiO2 Nanodots

被引:47
作者
Luo, Ming [1 ]
Cheng, Kui [1 ]
Weng, Wenjian [1 ]
Song, Chenlu [1 ]
Du, Piyi [1 ]
Shen, Ge [1 ]
Xu, Gang [1 ]
Han, Gaorong [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
来源
NANOSCALE RESEARCH LETTERS | 2009年 / 4卷 / 08期
关键词
TiO2; Eu3+; Nanodots; Phase-separation-induced self-assembly; Luminescence; TITANIA THIN-FILMS; SURFACE TENSION; ENERGY-TRANSFER; PHOTOLUMINESCENCE; PHOSPHORS; EMISSION; CELLS;
D O I
10.1007/s11671-009-9319-5
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Monodisperse and spherical Eu-doped TiO2 nanodots were prepared on substrate by phase-separation-induced self-assembly. The average diameters of the nanodots can be 50 and 70 nm by changing the preparation condition. The calcined nanodots consist of an amorphous TiO2 matrix with Eu3+ ions highly dispersed in it. The Eu-doped TiO2 nanodots exhibit intense luminescence due to effective energy transfer from amorphous TiO2 matrix to Eu3+ ions. The luminescence intensity is about 12.5 times of that of Eu-doped TiO2 film and the luminescence lifetime can be as long as 960 mu s.
引用
收藏
页码:809 / 813
页数:5
相关论文
共 25 条
[1]  
Benard H., 1900, REV GEN SCI PURES AP, V11, P1261, DOI DOI 10.1051/JPHYSTAP:019000090051300
[2]   SURFACE TENSION AS THE CAUSE OF BENARD CELLS AND SURFACE DEFORMATION IN A LIQUID FILM [J].
BLOCK, MJ .
NATURE, 1956, 178 (4534) :650-651
[3]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[4]   Luminescence behavior of pulsed laser deposited Eu:Y2O3 thin film phosphors on sapphire substrates [J].
Cho, KG ;
Kumar, D ;
Holloway, PH ;
Singh, RK .
APPLIED PHYSICS LETTERS, 1998, 73 (21) :3058-3060
[5]   Photoluminescence properties of the Eu3+ activator ion in the TiO2 host matrix [J].
Conde-Gallardo, A ;
García-Rocha, M ;
Hernández-Calderón, I ;
Palomino-Merino, R .
APPLIED PHYSICS LETTERS, 2001, 78 (22) :3436-3438
[6]   A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods [J].
Danielson, E ;
Devenney, M ;
Giaquinta, DM ;
Golden, JH ;
Haushalter, RC ;
McFarland, EW ;
Poojary, DM ;
Reaves, CM ;
Weinberg, WH ;
Wu, XD .
SCIENCE, 1998, 279 (5352) :837-839
[7]   Visible and near-IR luminescence via energy transfer in rare earth doped mesoporous titania thin films with nanocrystalline walls [J].
Frindell, KL ;
Bartl, MH ;
Robinson, MR ;
Bazan, GC ;
Popitsch, A ;
Stucky, GD .
JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (01) :81-88
[8]  
Frindell KL, 2002, ANGEW CHEM INT EDIT, V41, P959, DOI 10.1002/1521-3773(20020315)41:6<959::AID-ANIE959>3.0.CO
[9]  
2-M
[10]   Luminescence of pulsed laser deposited Eu doped yttrium oxide films [J].
Jones, SL ;
Kumar, D ;
Singh, RK ;
Holloway, PH .
APPLIED PHYSICS LETTERS, 1997, 71 (03) :404-406