Fluorinated emulsions:: Templates for the direct preparation of macroporous-mesoporous silica with a highly ordered array of large mesopores

被引:29
作者
Blin, J. L.
Bleta, R.
Ghanbaja, J.
Stebe, M. J. [1 ]
机构
[1] Univ Nancy 1, UMR 7565, Equipe Phys Chim Colloides, Nancy, France
[2] Fac Sci, Serv Commun Microscopie Electron, F-54506 Vandoeuvre Les Nancy, France
关键词
hierarchical porosity; silica; emulsion; fluorinated surfactant; ordered mesopores;
D O I
10.1016/j.micromeso.2006.03.023
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this paper, we report the use of oil/water (O/W) fluorinated emulsions to design macroporous-mesoporous silica with a well-ordered array of mesopores. The emulsion is constituted of fluorocarbon droplets stabilized by the fluorinated surfactant molecules and dispersed in an O/W fluorinated microemulsion. A macroporous texture is clearly evidenced by SEM. The size of the macropores varies from 1.0 to 3.0 mu m. SAXS patterns of the materials and TEM experiments show that the mesoporous network adopts a hexagonal arrangement. A type IV isotherm is obtained by nitrogen adsorption-desorption analysis. The mesopore size distribution is narrow and centered on about 7.5 nm. We also proposed a mechanism to explain the formation of these hierarchically structured macroporous-mesoporous silicas. (c) 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码:74 / 80
页数:7
相关论文
共 46 条
[1]   Monolithic periodic mesoporous silica with well-defined macropores [J].
Amatani, T ;
Nakanishi, K ;
Hirao, K ;
Kodaira, T .
CHEMISTRY OF MATERIALS, 2005, 17 (08) :2114-2119
[2]  
[Anonymous], 1994, SURFACTANT SCI SERIE
[3]   Synthesis of macro-mesoporous niobium oxide molecular sieves by a ligand-assisted vesicle templating strategy [J].
Antonelli, DM .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 33 (1-3) :209-214
[4]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[5]  
Blanford CF, 2001, ADV MATER, V13, P401, DOI 10.1002/1521-4095(200103)13:6<401::AID-ADMA401>3.0.CO
[6]  
2-7
[7]  
Blin J.L., 2003, ANGEW CHEM INT EDIT, V42, P1644
[8]   Effect of fluorocarbon addition on the structure and pore diameter of mesoporous materials prepared with a fluorinated surfactant [J].
Blin, JL ;
Stébé, MJ .
MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 87 (01) :67-76
[9]   Perfluorodecalin incorporation in fluorinated surfactant-water system:: Tailoring of mesoporous materials pore size [J].
Blin, JL ;
Stébe, MJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (31) :11399-11405
[10]   Nonionic fluorinated surfactant:: Investigation of phase diagram and preparation of ordered mesoporous materials [J].
Blin, JL ;
Lesieur, P ;
Stébé, MJ .
LANGMUIR, 2004, 20 (02) :491-498