Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)]

被引：4

作者：

Sun, Xiaodan ^{[1
]}

He, Xianhua ^{[1
]}

Wang, Wei ^{[1
]}

Miao, Donghua ^{[1
]}

Sun, Qiaozhen ^{[1
]}

机构：

[1] Cent S Univ, Minist Educ, Dept Chem Mat, Sch Mat Sci & Engn,Key Lab Nonferrous Met, Changsha 410083, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

SCHIFF-BASE; CRYSTAL-STRUCTURES; COMPLEXES; LIGANDS; TRIAZOLE; 3-DIMENSIONALITY; CONSTRUCTION;

D O I：

10.1107/S1600536809013130

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, {[Zn(C(9)H(9)N(5))(2)(H(2)O)(2)](ClO(4))(2)}(n), the Zn(II) ion lies on an inversion center and is coordinated by two triazolyl N atoms and two pyridyl N atoms from four symmetry-related N-1-(3-pyridyl)ethylidene-4H-1,2,4-triazol-4-amine (L) ligands and two O atoms from coordinated water molecules in a slightly distorted octahedral environment. Each L ligand bridges symmetry-related Zn(II) ions, forming a two-dimensional layer with a (4,4) grid. In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds connect perchlorate counter-anions to the layers.

引用

页码：M518 / U535

页数：12

共 19 条

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[2]

2-Z

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