Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters

被引：162

作者：

Lyubov, Dmitry M. ^{[1
]}

Tolpygin, Aleksey O. ^{[1
]}

Trifonov, Alexander A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Inst Organometall Chem, Tropinina Str 49,GSP-445, Nizhnii Novgorod 630950, Russia

[2] Russian Acad Sci, Inst Organoelement Cpds, Vavilova Str 28, Moscow 119334, Russia

来源：

COORDINATION CHEMISTRY REVIEWS | 2019年 / 392卷

基金：

俄罗斯基础研究基金会;

关键词：

EPSILON-CAPROLACTONE POLYMERIZATION; L-LACTIDE POLYMERIZATION; AMIDINATE LIGANDS SYNTHESIS; HIGHLY-ACTIVE INITIATORS; IN-SITU FORMATION; BIS(PHENOLATE) LANTHANIDE COMPLEXES; YTTRIUM PHOSPHASALEN INITIATORS; SINGLE-COMPONENT CATALYSTS; N; O MULTIDENTATE LIGANDS; RAC-LACTIDE;

D O I：

10.1016/j.ccr.2019.04.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review is focused on recent advances in the ring-opening polymerization of lactide and lactones (mainly caprolactone and beta-butyrolactone) which were achieved due to the application of the initiating systems based on rare-earth complexes. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：83 / 145

页数：63

共 382 条

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[2]

2-1

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