Catalytic Reduction of Nitriles by Polymethylhydrosiloxane Using a Phenalenyl-Based Iron(III) Complex

被引：24

作者：

Das, Shyamal ^{[1
]}

Das, Hari Sankar ^{[1
]}

Singh, Bhagat ^{[1
]}

Haridasan, Rahul Koottanil ^{[1
]}

Das, Arpan ^{[1
]}

Mandal, Swadhin K. ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Kolkata, Dept Chem Sci, Mohanpur 741246, India

来源：

INORGANIC CHEMISTRY | 2019年 / 58卷 / 17期

关键词：

PRIMARY AMINES; SELECTIVE HYDROGENATION; AROMATIC NITRILES; METAL-CATALYSTS; CLOSED-SHELL; HYDROSILYLATION; AMINATION; SECONDARY; EFFICIENT; ALCOHOLS;

D O I：

10.1021/acs.inorgchem.9b01377

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of nitriles to primary amines using an inexpensive silane such as polymethylhydrosiloxane (PMHS) is an industrially important reaction. Herein we report the synthesis of an earth-abundant Fe(III) complex bearing a phenalenyl-based ligand that was characterized by mass spectroscopy, elemental analysis, cyclic voltammetry, and single-crystal X-ray diffraction. The complex showed excellent catalytic activity toward reduction of aromatic, heteroaromatic, aliphatic, and sterically crowded nitriles to produce primary amines using polymethylhydrosiloxane (PMHS).

引用

页码：11274 / 11278

页数：5

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